{"title":"Quasi-aromatic clathrochelate-centered radicals: preparation, reactivity, and prospects for practical application","authors":"A. S. Chuprin","doi":"10.1007/s11172-024-4433-1","DOIUrl":null,"url":null,"abstract":"<div><p>The review is devoted to the main synthetic strategies and optimal methods for preparation of persistent clathrochelate-centered radicals, the macrobicyclic products of free-radical reactions of the clathrochelate precursors. Prospects for practical applications of this type of compounds as radical polymerization initiators and paramagnetic probes for MRI and EPR studies are analyzed.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 11","pages":"3176 - 3189"},"PeriodicalIF":1.7000,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4433-1","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The review is devoted to the main synthetic strategies and optimal methods for preparation of persistent clathrochelate-centered radicals, the macrobicyclic products of free-radical reactions of the clathrochelate precursors. Prospects for practical applications of this type of compounds as radical polymerization initiators and paramagnetic probes for MRI and EPR studies are analyzed.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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