Host-Matrix Interactions and Molecular Functionalization: Shaping the Delayed Emission Properties of Indenophenanthridine Derivatives.

IF 3 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ChemPlusChem Pub Date : 2025-01-15 DOI:10.1002/cplu.202400571

Prasannamani Govindharaj, Jamuna Kannan, Sivakumar Shanmugam, Przemysław Data

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引用次数: 0

Abstract

The advancement of organic room temperature phosphorescence (RTP) materials has attracted considerable interest owing to their extensive applications. Their distinct advantages, including a metal-free composition, low toxicity, and facile synthesis under ambient conditions, make them highly desirable. This study examines the delayed fluorescence (DF) and RTP of metal-free, amorphous indenophenanthridine (IND)-based derivatives (1-10) and provides insights into molecular functionalisation and host matrix effects on delayed emission (RTP and DF). IND derivatives have been used in bioimaging and organic analyte detections; however, their delayed emission mechanism photophysical processes are poorly understood. This work examines the derivatives' physicochemical properties and time-resolved photophysics to determine how molecular structure, host interaction, and delayed emission properties relate. The described IND compounds show RTP and/or TTA (triplet-triplet annihilation) delayed fluorescence depending on the host environment. This research lays the groundwork for designing and developing new materials with increased RTP efficiency for future applications by detailing the detailed RTP processes and the crucial function of the host matrix.

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来源期刊

ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

5.90

自引率

0.00%

发文量

200

审稿时长

1 months

期刊介绍： ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.