Emily Howarth, Jordan Lopez, Joseph O. Ogar, Toby J. Blundell, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Yoshihiko Ihara, Simon J. Coles, Peter N. Horton, Jeppe Christensen, Lee Martin
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引用次数: 0
Abstract
This paper reports the synthesis, crystal structures and conducting properties of the first BEDT-TTF radical-cation salts with D3 symmetry tris-coordinated racemic lanthanide(III) anions. It is also the first crystallographic determination of the nine-coordinate tris(chelidonato)terbate and tris(chelidonato)dysprosate anions (chelidonic acid = clo = 4-oxo-4H-pyran-2,6-dicarboxylic acid). Salt α-(BEDT-TTF)5M(chelidonato)3·EtOH·2H2O is semimetallic for M = Tb, and semiconducting for M = Dy. These conducting properties are consistent with the band structure for both salts.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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