{"title":"DNDMH Enabled C(sp3)−H Nitration of Aryl Alkenes","authors":"Zhiyuan Wang, Yali Li, Xuena Ding, Yuancheng Sun, Chongchong Chen, Wei Sun, Xiangdong Hu","doi":"10.1039/d4cc06671e","DOIUrl":null,"url":null,"abstract":"C(sp3)−H bond nitration opens facile access to nitro compounds unreachable from traditional nitration pathway. The work describes herein a C(sp3)−H bond nitration of aryl alkenes with the application of DNDMH, a nitration reagent developed previously in our lab. Notably, this novel nitration process presents good regioselectivity and chemoselectivity between C(sp3)−H nitration and C(sp2)−H nitration.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"15 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc06671e","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
C(sp3)−H bond nitration opens facile access to nitro compounds unreachable from traditional nitration pathway. The work describes herein a C(sp3)−H bond nitration of aryl alkenes with the application of DNDMH, a nitration reagent developed previously in our lab. Notably, this novel nitration process presents good regioselectivity and chemoselectivity between C(sp3)−H nitration and C(sp2)−H nitration.
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