Short-term supercritical heat transfer: In memory of Anneke Levelt Sengers

IF 3.4 3区 工程技术 Q2 CHEMISTRY, PHYSICAL Journal of Supercritical Fluids Pub Date : 2025-01-03 DOI:10.1016/j.supflu.2025.106516
Pavel Skripov , Sergey Rutin , Lin Chen
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Abstract

The paper is dedicated to the memory of Anneke Levelt Sengers (Johanna/Anneke/Maria Henrica Levelt, 1929–2024), a world-renowned scientist on liquid-vapor critical phenomena. It summarizes the results of pulse heating experiments performed under conditions of short-term (units of ms) powerful heat release in supercritical-pressure water. The pressure, being the parameter of the experiment, was varied from a near-supercritical value (22.1 MPa) to 100 MPa. Initial temperature was 25 ºC, while its rise in the course of a pulse ranged from 230 ºC up to 680 ºC. Results obtained for pulse heating along the supercritical isobars are based solely on comparison with primary data. The surprising feature of the results is that a threshold drop in the intensity of heat transfer near the critical temperature occurs and becomes deeper, as the pressure approaches the supercritical pressure. The aim of the present paper is to suggest a relatively simple approach to reconciling pulse heating results with well-known peaks of thermophysical properties derived from experiments under stationary conditions. The variant suggested of such approach is based on the hypotheses of suppression of large-scale fluctuations in fast processes and the additional thermal resistance accompanying by the appearance of structural non-uniformity in an initially homogeneous fluid.
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短期超临界传热:纪念安内克液位传感器
这篇论文是为了纪念世界著名的液体-蒸汽临界现象科学家Anneke Levelt seners (Johanna/Anneke/Maria Henrica Levelt, 1929-2024)。总结了在超临界压力水中短时间(以毫秒为单位)强放热条件下脉冲加热实验的结果。压力作为实验参数,从近超临界值(22.1 MPa)变化到100 MPa。初始温度为25ºC,而其在脉冲过程中的上升范围从230ºC到680ºC。沿超临界等压线的脉冲加热结果完全基于与原始数据的比较。结果的惊人特征是,在临界温度附近,传热强度的阈值下降发生,并且随着压力接近超临界压力而变得更深。本文的目的是提出一种相对简单的方法来调和脉冲加热结果与在固定条件下从实验中得到的众所周知的热物理性质峰值。这种方法的变体是基于在快速过程中抑制大规模波动的假设,以及在最初均匀的流体中伴随结构不均匀性出现的额外热阻。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Supercritical Fluids
Journal of Supercritical Fluids 工程技术-工程:化工
CiteScore
7.60
自引率
10.30%
发文量
236
审稿时长
56 days
期刊介绍: The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics. Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.
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