Decarbonizing specialty chemical manufacturing: opportunities for electrochemists†

Robert J. Hacku, Thomas J. Henry, Michael A. Kane, Maxwell J. Vance, Zachary J. Sebastian, Glenn Cormack, Tyler J. Petek, Elisa Seddon and James R. McKone
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Abstract

To meet global decarbonization goals, the chemical industry faces the challenge of dramatically reducing greenhouse gas emissions even as demand for chemical products continues to grow. This challenge is amplified by the sector's reliance on petroleum-based hydrocarbons as both fuel and feedstock. Electrochemical synthesis is widely viewed as an attractive method to decarbonize chemical manufacturing through the use of low-carbon electricity to drive redox reactions. Presently, much of the work in this area is focused on electrochemical strategies to produce commodity chemicals. In this work, we make the case that developing electrosynthetic methods for specialty chemical manufacturing is another attractive entry point for electrochemical process design. We further outline the results of a scoping study aimed at assessing the potential to decarbonize the production of several organic compounds that are widely used in specialty chemical manufacturing by using electrochemical reactors. Our approach entails mapping the supply chain for each compound back to its petrochemical feedstock, identifying opportunities to incorporate electrochemical transformations along the supply chain, and estimating the potential for decarbonization through the adoption of electrosynthetic schemes. The results show there already exist significant opportunities to decarbonize specialty chemical transformations today, even under very conservative assumptions about process efficiency and the carbon intensity of the input electricity.

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脱碳特种化学品制造:电化学家的机会†
为了实现全球脱碳目标,即使对化学产品的需求持续增长,化学工业也面临着大幅减少温室气体排放的挑战。该行业对石油基碳氢化合物作为燃料和原料的依赖加剧了这一挑战。电化学合成被广泛认为是一种有吸引力的方法,通过使用低碳电来驱动氧化还原反应来脱碳化学制造。目前,该领域的大部分工作都集中在生产商品化学品的电化学策略上。在这项工作中,我们提出了开发特殊化学品制造的电合成方法是电化学过程设计的另一个有吸引力的切入点。我们进一步概述了一项范围研究的结果,该研究旨在评估利用电化学反应器对几种广泛用于特种化学品制造的有机化合物进行脱碳生产的潜力。我们的方法需要将每种化合物的供应链映射回其石化原料,确定沿供应链合并电化学转换的机会,并通过采用电合成方案估计脱碳的潜力。结果表明,即使在对工艺效率和输入电力的碳强度非常保守的假设下,今天已经存在重大的脱碳特殊化学转化的机会。
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Inside back cover Back cover Afterglow quenching in plasma-based dry reforming of methane: a detailed analysis of the post-plasma chemistry via kinetic modelling. Showcasing the technological advancements of carbon dioxide conversion: a pathway to a sustainable future From lead–acid batteries to perovskite solar cells – efficient recycling of Pb-containing materials†
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