Impact of Compatibilizer on the Electrical and Thermal Characteristics of Areca Fibre-Filled Polypropylene Composites

IF 2.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Fibers and Polymers Pub Date : 2024-12-04 DOI:10.1007/s12221-024-00791-2
Madhushri Attihalli Venkatachalaiah, Raju Nama Vasudeva Setty, Jobish Johns, Gajanan V. Honnavar, M. V. Murugendrappa
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Abstract

This study examines the effects of the coupling agent maleic anhydride-grafted polypropylene on the thermal and dielectric properties of areca–polypropylene composites. Test specimens of both uncoupled and coupled composites were prepared using injection molding methods in accordance with ASTM standards, with filler percentages ranging from 20 to 50%. Dielectric characteristics were evaluated across frequencies ranging from 10 Hz to 10 MHz and temperatures from 30 °C to 120 °C at 10 °C intervals. The results showed enhanced dielectric properties in the maleic anhydride-grafted polypropylene composites due to improved fibre dispersion and polarization mechanisms. These composites, with their high dielectric constants, have potential applications in gate dielectrics, actuators, sensors, and more. The morphology and chemical composition were analyzed using scanning electron microscopy and Fourier transform infrared spectroscopy, while thermogravimetric analysis and water diffusion coefficient tests confirmed the successful grafting of the coupling agent onto the fibres.

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增容剂对槟榔纤维填充聚丙烯复合材料电学和热学特性的影响
研究了偶联剂马来酸酐接枝聚丙烯对槟榔-聚丙烯复合材料热性能和介电性能的影响。未偶联和偶联复合材料的试样均按照ASTM标准采用注射成型方法制备,填充率为20% ~ 50%。在频率范围为10 Hz至10 MHz,温度范围为30°C至120°C的10°C间隔内评估介电特性。结果表明,马来酸酐接枝聚丙烯复合材料的介电性能增强是由于纤维分散和极化机制的改善。这些复合材料具有高介电常数,在栅极电介质、执行器、传感器等方面具有潜在的应用前景。利用扫描电镜和傅里叶变换红外光谱分析了偶联剂的形貌和化学成分,热重分析和水扩散系数测试证实了偶联剂成功接枝到纤维上。
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来源期刊
Fibers and Polymers
Fibers and Polymers 工程技术-材料科学:纺织
CiteScore
3.90
自引率
8.00%
发文量
267
审稿时长
3.9 months
期刊介绍: -Chemistry of Fiber Materials, Polymer Reactions and Synthesis- Physical Properties of Fibers, Polymer Blends and Composites- Fiber Spinning and Textile Processing, Polymer Physics, Morphology- Colorants and Dyeing, Polymer Analysis and Characterization- Chemical Aftertreatment of Textiles, Polymer Processing and Rheology- Textile and Apparel Science, Functional Polymers
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