A cell level design and analysis of lithium-ion battery packs

IF 2.4 4区 化学 Q3 CHEMISTRY, PHYSICAL Ionics Pub Date : 2024-10-31 DOI:10.1007/s11581-024-05908-4
Harish S., P. Uma Sathyakam
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Abstract

The world is gradually adopting electric vehicles (EVs) instead of internal combustion (IC) engine vehicles that raise the scope of battery design, battery pack configuration, and cell chemistry. Rechargeable batteries are studied well in the present technological paradigm. The current investigation model simulates a Li-ion battery cell and a battery pack using COMSOL Multiphysics with built-in modules of lithium-ion batteries, heat transfer, and electrochemistry. This model aims to study the influence of the cell’s design on the cell’s temperature changes and charging and discharging thermal characteristics and thermal runaway propagation characteristics of a battery and a battery pack composed of 18,650 and 4680 cylindrical batteries. The charge and discharge C-rates are varied. An event-based thermal runaway of the cell and a battery pack is presented finally. Based on the findings, it can be determined that the cell’s temperature is closely connected to the geometry of the cell, the C-rate, the active mass loading of the electrodes, and the operating temperature. For 18,650 and 4680 types, a projected capacity is 2.71 Ah and 21.8 Ah, heat generated is 1.19 Wh and 3.44 Wh, and the cell temperature at a constant discharge rate of 1C is 21.08 °C and 147.57 °C respectively. 4680 battery occupies four times less space, eight times less number of cells, and 20% less current collector materials utilized than the 18,650 battery, for a common capacity of 100 KWh.

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锂离子电池组的电池级设计与分析
世界正在逐步采用电动汽车(ev),而不是内燃机汽车(IC),这提高了电池设计、电池组配置和电池化学的范围。可充电电池在目前的技术范式下得到了很好的研究。目前的研究模型使用COMSOL Multiphysics模拟锂离子电池和电池组,内置锂离子电池、传热和电化学模块。本模型旨在研究电芯设计对电池芯温度变化、充放电热特性和热失控传播特性的影响,研究由18650和4680圆柱形电池组成的电池组。充放电倍率各不相同。最后提出了基于事件的电池和电池组热失控问题。基于这些发现,可以确定电池的温度与电池的几何形状、c率、电极的有效质量负荷和工作温度密切相关。18650型和4680型的预计容量分别为2.71 Ah和21.8 Ah,发热量分别为1.19 Wh和3.44 Wh,放电倍率为1C时的电池温度分别为21.08℃和147.57℃。4680电池占用的空间比18650电池少四倍,电池数量少八倍,集电极材料用量少20%,而普通容量为100千瓦时。
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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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