Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes

IF 4.1 2区 化学 Q2 POLYMER SCIENCE Chinese Journal of Polymer Science Pub Date : 2024-12-25 DOI:10.1007/s10118-024-3247-9
N. V. Zakharova, G. K. Lebedeva, N. N. Saprykina, E. V. Kruchinina, E. A. Novozhilova, S. V. Kononova
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Abstract

Porous phase-inversion membranes of complex morphology were obtained on the basis of aromatic polyamidoimides with different numbers of hydroxyl groups in the diamine component of the repeating unit. The influence of the quality of the precipitant (nonsolvent) applied in membrane preparation (i.e., the use of “strong” or “weak” nonsolvent) on structural and morphological features of polymer membranes of various chemical compositions was studied. Investigation of dilute solutions of membrane-forming polymers by optical methods revealed the changes in the state of the system both in the presence of a solvent and in the presence of a nonsolvent. On the basis of the obtained results, it was possible to estimate the sensitivity of the studied polymer/solvent/nonsolvent system to changes in the copolymer composition (a number of hydroxyl groups in the repeating unit).

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沉淀剂种类对反相聚酰胺-亚胺膜结构的影响
以重复单元的二胺组分中羟基数目不同的芳香族聚酰胺酰亚胺为基础,制备了具有复杂形态的多孔反相膜。研究了膜制备中使用的沉淀剂(非溶剂)的质量(即“强”或“弱”非溶剂的使用)对不同化学成分聚合物膜结构和形态特征的影响。用光学方法研究成膜聚合物的稀溶液,揭示了在溶剂和非溶剂存在下系统状态的变化。根据得到的结果,可以估计所研究的聚合物/溶剂/非溶剂体系对共聚物组成(重复单元中羟基的数量)变化的敏感性。
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来源期刊
Chinese Journal of Polymer Science
Chinese Journal of Polymer Science 化学-高分子科学
CiteScore
7.10
自引率
11.60%
发文量
218
审稿时长
6.0 months
期刊介绍: Chinese Journal of Polymer Science (CJPS) is a monthly journal published in English and sponsored by the Chinese Chemical Society and the Institute of Chemistry, Chinese Academy of Sciences. CJPS is edited by a distinguished Editorial Board headed by Professor Qi-Feng Zhou and supported by an International Advisory Board in which many famous active polymer scientists all over the world are included. The journal was first published in 1983 under the title Polymer Communications and has the current name since 1985. CJPS is a peer-reviewed journal dedicated to the timely publication of original research ideas and results in the field of polymer science. The issues may carry regular papers, rapid communications and notes as well as feature articles. As a leading polymer journal in China published in English, CJPS reflects the new achievements obtained in various laboratories of China, CJPS also includes papers submitted by scientists of different countries and regions outside of China, reflecting the international nature of the journal.
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