Isolation, structural characterization of (1 → 4), (1 → 6)-α-D-glucan from Dioscorea Alata and synthesis and catalytic activity studies of (1 → 4), (1 → 6)-α-D-glucan derived carbon dots.

Abstract

Herein, a straightforward, productive protocol was adopted for the synthesis of carbon dots (CDs) by a simple microwave-assisted technique from (1 → 4), (1 → 6)-α-D-glucan polysaccharide (DAPS). The isolation and structural characterization of (1 → 4), (1 → 6)-α-D-glucan from the aqueous extracting of the Diascorea Alata was described here. The photo-physical and morphological studies of the prepared high quantum yield (27.70 %) CDs were systematically characterized using different analytical techniques: TEM, DLS, XPS, XRD, FT-IR, TCSPC, EDX, Fluorescence and UV-vis spectroscopy. In our study the carbon dots (CDs) obtained are non-toxic, highly water-soluble, spherical-shaped negatively charged particles with an average diameter of 3.28 nm. The photo-catalytic activity of carbon dots (CDs) was tested under the sunlight for photo-degradation of crystal violet (CV), a pollutant organic dye. Carbon dots (CDs) showed outstanding results regarding the photo degradation of CV (achieving 99.9 % degradation within 8 min) under sunlight.