Advances and challenges in recycling spent LiFePO4 batteries

IF 9 1区 工程技术 Q1 ENGINEERING, CHEMICAL Separation and Purification Technology Pub Date : 2025-01-23 DOI:10.1016/j.seppur.2025.131780
Biyun Luo , Bin Xu , Qunxuan Yan , Yujiuan Zhou , Zhongling Dong , Xiujiao Huang , Zixiang Zhao
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Abstract

The intensive growth and finite lifespan of electric vehicle have brought about the concomitantly exponential generation of scrapped lithium-ion batteries (LIB). Lithium iron phosphate (LFP) batteries account for a large proportion of spent LIB. However, their actual recycling volume is relatively low due to the limited economic value of recycling. With the increasing environmental and economic benefits of recycling spent LIB, the recovery of spent lithium iron phosphate (sLFP) batteries is becoming a hot research field, with a variety of innovative green recycling technologies emerging.
This review described the leaching mechanism of LIB, and evaluated the advantages and limitations of various recycling technologies for sLFP batteries (Pyrometallurgy, Hydrometallurgy, Direct regeneration, Electrochemical technology). In addition, the recycling method, challenges, and developing tendency of battery recycling are put presented and analyzed.

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废旧LiFePO4电池回收的进展与挑战
随着电动汽车的集约化发展和有限的使用寿命,废旧锂离子电池的数量也呈指数级增长。磷酸铁锂(LFP)电池占废旧锂电池的很大比例。但由于回收利用的经济价值有限,其实际回收量相对较低。随着废旧锂电池回收利用的环境效益和经济效益不断提高,废旧磷酸铁锂电池的回收利用正成为一个研究热点,各种创新的绿色回收技术层出不穷。综述了锂离子电池的浸出机理,并对sLFP电池的各种回收技术(火法冶金、湿法冶金、直接再生、电化学技术)的优缺点进行了评价。此外,对电池回收的方法、面临的挑战和发展趋势进行了介绍和分析。
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来源期刊
Separation and Purification Technology
Separation and Purification Technology 工程技术-工程:化工
CiteScore
14.00
自引率
12.80%
发文量
2347
审稿时长
43 days
期刊介绍: Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.
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