Marceline Humbert, Arnaud Clerc, Karinne Miqueu, Julien Monot, Blanca Maria Martin Vaca, Didier Bourissou
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引用次数: 0
Abstract
E–H Bond activation (E = B, Ge, Sn) with a (PNS)Pd complex has been investigated theoretically and experimentally. Et3GeH readily adds across the Pd/S bond. Subsequent transfer to C≡C bonds enables catalytic hydrogermylation. The reaction is most regio and stereoselective with terminal alkynes. Downstrean derivatization of silyl-functionalized vinyl germanes is exemplified.
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