Maillard reaction inducing amino acids degradation can adjust the flavour characteristic of black tea.

IF 8 Food research international (Ottawa, Ont.) Pub Date : 2025-02-01 Epub Date: 2025-01-06 DOI:10.1016/j.foodres.2025.115685
Li Li, Jiezhong Zan, Wenxue Chen, Xuyan Zong, Haibo Yuan, Yongwen Jiang, Hongkai Zhu
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Abstract

Drying is the step that is to be used to adjust and control the formation of flavour and quality in black tea processing. In the present work, the comprehensive two-dimensional gas chromatography with mass spectrometry (GC × GC-MS) and gas chromatography olfactometry with mass (GC-O-MS) were used to determine the dynamic change of the volatile compounds in black tea during drying at 90, 120, 150 °C for 1 h. Results showed that the ratio of esters and aldehydes largely declined when temperature was elevated from 90 °C to 150 °C, while the ratio of heterocycles was increased to 22.4 % from 16.5 %. A total of 15 key aroma activity volatiles were screened out in three temperature dried samples, therein 11 volatiles were connected with the Maillard reaction, meaning these volatiles were highly relevant to the degradation of amino acids during the drying process. We detected that 21 amino acids were decreased with enhanced temperature and extended the drying time, which promoted the Maillard-derived volatiles formation. Therefore, it was suggested that to control the degradation of amino acids adjust the flavour profiles of black tea by changing the drying temperature and time.

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美拉德反应诱导氨基酸降解可调节红茶的风味特性。
干燥是红茶加工过程中调节和控制风味和品质形成的步骤。在目前的工作,综合二维气相色谱与质谱(GC×GC - ms)、气相色谱嗅觉测量法和质量(GC-O-MS)被用来确定动态变化的挥发性化合物在红茶干燥在90、120、150°C 1 h。结果表明,酯类和醛很大程度上拒绝的比例从90°C当温度升高到150°C,而杂环化合物的比例从22.4%增加到16.5%。在3种温度干燥样品中共筛选出15种关键香气活性挥发物,其中11种挥发物与美拉德反应有关,说明这些挥发物与干燥过程中氨基酸的降解高度相关。结果表明,随着温度的升高和干燥时间的延长,有21种氨基酸含量减少,促进了美拉德衍生挥发物的形成。因此,建议通过改变干燥温度和干燥时间来控制氨基酸的降解,调节红茶的风味特征。
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