Interfacial creation of positively charged sites in LaPO4/Fe3(PO4)2 heterojunctions for high-current-density oxygen evolution†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-01-25 DOI:10.1039/D5CC00018A
Sitong Liu, Yudi Zhang, Wen Sun, Junqiang Wang, Dengsong Zhang, Juntao Huo and Guowei Li
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Abstract

The creation of positively charged active sites is crucial for enhancing the adsorption of negatively charged hydroxide ions, thereby improving the sluggish oxygen evolution reaction (OER). We engineered LaPO4/Fe3(PO4)2 heterojunctions with a low flat-band potential, facilitating interfacial charge transfer and generation of positively charged holes, resulting in a highly active and stable OER catalyst at 500 mA cm−2.

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高电流密度析氧用LaPO₄/Fe₃(PO₄)₂异质结中正电荷位点的界面形成
带正电的活性位点的产生对于增强带负电的氢氧根离子的吸附至关重要,从而改善缓慢的析氧反应(OER)。我们设计了具有低平带电位的LaPO₄/Fe₃(PO₄)₂异质结,促进了界面电荷转移和正电荷空穴的产生,从而产生了500 mA cm⁻²的高活性和稳定的OER催化剂。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
期刊最新文献
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