Chemical and thermal stability of thermoplastics in fast and mixed irradiation extremes

IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Radiation Physics and Chemistry Pub Date : 2025-01-16 DOI:10.1016/j.radphyschem.2025.112533
Andrea Labouriau, Loren Espada-Castillo, John R. Stockdale, Adam Pacheco, Shelbie A. Legett, Steve Simmonds, Clinton Shonrock, Santosh Adhikari
{"title":"Chemical and thermal stability of thermoplastics in fast and mixed irradiation extremes","authors":"Andrea Labouriau,&nbsp;Loren Espada-Castillo,&nbsp;John R. Stockdale,&nbsp;Adam Pacheco,&nbsp;Shelbie A. Legett,&nbsp;Steve Simmonds,&nbsp;Clinton Shonrock,&nbsp;Santosh Adhikari","doi":"10.1016/j.radphyschem.2025.112533","DOIUrl":null,"url":null,"abstract":"<div><div>This study examines the stability of thermoplastics when submitted to high neutron and electron beam fluxes. Two thermoplastics were investigated, ultra-high molecular weight polyethylene (UHMWPE) containing up to 40 wt % isotopically enriched boron-10, and 3D printed acrylonitrile butadiene styrene (ABS) containing 60 wt % tungsten. FT-IR of exposed borated-UHMWPE showed small changes to its chemical structure due to oxidative degradation. Whereas thermal gravimetric analysis (TGA) indicated that about 15 wt% of tungsten was removed from the surface of 3D printed W-ABS that was directly facing the electron beam. This effect is due to the rapid energy deposition on the metal causing ablation. This study demonstrates that these two thermoplastics are not only useful in multiple industrial applications, but are also fairly resilient to extreme radiation environments.</div></div>","PeriodicalId":20861,"journal":{"name":"Radiation Physics and Chemistry","volume":"229 ","pages":"Article 112533"},"PeriodicalIF":2.8000,"publicationDate":"2025-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiation Physics and Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0969806X25000258","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

This study examines the stability of thermoplastics when submitted to high neutron and electron beam fluxes. Two thermoplastics were investigated, ultra-high molecular weight polyethylene (UHMWPE) containing up to 40 wt % isotopically enriched boron-10, and 3D printed acrylonitrile butadiene styrene (ABS) containing 60 wt % tungsten. FT-IR of exposed borated-UHMWPE showed small changes to its chemical structure due to oxidative degradation. Whereas thermal gravimetric analysis (TGA) indicated that about 15 wt% of tungsten was removed from the surface of 3D printed W-ABS that was directly facing the electron beam. This effect is due to the rapid energy deposition on the metal causing ablation. This study demonstrates that these two thermoplastics are not only useful in multiple industrial applications, but are also fairly resilient to extreme radiation environments.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
求助全文
约1分钟内获得全文 去求助
来源期刊
Radiation Physics and Chemistry
Radiation Physics and Chemistry 化学-核科学技术
CiteScore
5.60
自引率
17.20%
发文量
574
审稿时长
12 weeks
期刊介绍: Radiation Physics and Chemistry is a multidisciplinary journal that provides a medium for publication of substantial and original papers, reviews, and short communications which focus on research and developments involving ionizing radiation in radiation physics, radiation chemistry and radiation processing. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. This could include papers that are very similar to previous publications, only with changed target substrates, employed materials, analyzed sites and experimental methods, report results without presenting new insights and/or hypothesis testing, or do not focus on the radiation effects.
期刊最新文献
Radiolytic behavior and effect in nuclear reactor coolants: A focus on ammonia and hydrazine Polymeric gamma rays shield promoted by ferrite nanoparticles synthesized with Ni and Zn cations Eco-friendly and low-dose radiation shielding material using natural waste cuttlebone and silicone rubber composite Experimental validation of absolute full energy peak efficiency and energy resolution of NaI(Tl), CsI(Tl), BGO, YAP(Ce) and CeBr3 scintillation detectors modeled with Monte Carlo codes Bentonite-clay bricks reinforced with fuel fly ash: Structural and gamma attenuation characterization
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1