Chemical and thermal stability of thermoplastics in fast and mixed irradiation extremes

IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Radiation Physics and Chemistry Pub Date : 2025-01-16 DOI:10.1016/j.radphyschem.2025.112533
Andrea Labouriau, Loren Espada-Castillo, John R. Stockdale, Adam Pacheco, Shelbie A. Legett, Steve Simmonds, Clinton Shonrock, Santosh Adhikari
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Abstract

This study examines the stability of thermoplastics when submitted to high neutron and electron beam fluxes. Two thermoplastics were investigated, ultra-high molecular weight polyethylene (UHMWPE) containing up to 40 wt % isotopically enriched boron-10, and 3D printed acrylonitrile butadiene styrene (ABS) containing 60 wt % tungsten. FT-IR of exposed borated-UHMWPE showed small changes to its chemical structure due to oxidative degradation. Whereas thermal gravimetric analysis (TGA) indicated that about 15 wt% of tungsten was removed from the surface of 3D printed W-ABS that was directly facing the electron beam. This effect is due to the rapid energy deposition on the metal causing ablation. This study demonstrates that these two thermoplastics are not only useful in multiple industrial applications, but are also fairly resilient to extreme radiation environments.
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热塑性塑料在快速和混合辐照极值下的化学和热稳定性
本研究考察了热塑性塑料在高中子和电子束通量下的稳定性。研究人员研究了两种热塑性塑料,一种是含有高达40 wt %同位素富集硼-10的超高分子量聚乙烯(UHMWPE),另一种是含有60 wt %钨的3D打印丙烯腈-丁二烯苯乙烯(ABS)。暴露的硼化超高分子量聚乙烯的FT-IR显示其化学结构由于氧化降解而发生了很小的变化。而热重分析(TGA)表明,3D打印W-ABS直接面对电子束的表面约有15 wt%的钨被去除。这种效应是由于快速的能量沉积在金属上引起烧蚀。这项研究表明,这两种热塑性塑料不仅在多种工业应用中有用,而且对极端辐射环境也有相当的弹性。
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来源期刊
Radiation Physics and Chemistry
Radiation Physics and Chemistry 化学-核科学技术
CiteScore
5.60
自引率
17.20%
发文量
574
审稿时长
12 weeks
期刊介绍: Radiation Physics and Chemistry is a multidisciplinary journal that provides a medium for publication of substantial and original papers, reviews, and short communications which focus on research and developments involving ionizing radiation in radiation physics, radiation chemistry and radiation processing. The journal aims to publish papers with significance to an international audience, containing substantial novelty and scientific impact. The Editors reserve the rights to reject, with or without external review, papers that do not meet these criteria. This could include papers that are very similar to previous publications, only with changed target substrates, employed materials, analyzed sites and experimental methods, report results without presenting new insights and/or hypothesis testing, or do not focus on the radiation effects.
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