Xin Jing, Xuebing Li, Yong Zhao, Quanliang Wang, Xiao Kang, Xiaojie Liu, Aziz Saparbaev, Feng Li, Mingliang Sun
{"title":"Effects of Additional Flexible and Rigid Structure on BDT-BDD Terpolymer and the Performance of Organic Solar Cells.","authors":"Xin Jing, Xuebing Li, Yong Zhao, Quanliang Wang, Xiao Kang, Xiaojie Liu, Aziz Saparbaev, Feng Li, Mingliang Sun","doi":"10.3390/polym17020248","DOIUrl":null,"url":null,"abstract":"<p><p>In organic solar cells, the aggregation and crystallization of polymers are significant for bulk heterojunction. Blending with acceptor materials, polymer donor materials can adjust their aggregation by the movement of the chain segments. In this paper, the unfused structures based on thiophene and carbazole are respectively designed and introduced into the donor-acceptor copolymer donor materials to investigate the influence of flexible and rigid structures on polymer-aggregation leading photoelectric performance. The material and quantum chemical property investigations show that the selection and design of the blocks are important for the properties of the terpolymers, and the resulting polymer:Y6 devices achieve improvements in performance from 13.85% to 15.66% (especially for fill factors from 63.37% up to 69.81%). This result contributes to designing and optimizing efficient polymers.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"17 2","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11769530/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymers","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.3390/polym17020248","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
In organic solar cells, the aggregation and crystallization of polymers are significant for bulk heterojunction. Blending with acceptor materials, polymer donor materials can adjust their aggregation by the movement of the chain segments. In this paper, the unfused structures based on thiophene and carbazole are respectively designed and introduced into the donor-acceptor copolymer donor materials to investigate the influence of flexible and rigid structures on polymer-aggregation leading photoelectric performance. The material and quantum chemical property investigations show that the selection and design of the blocks are important for the properties of the terpolymers, and the resulting polymer:Y6 devices achieve improvements in performance from 13.85% to 15.66% (especially for fill factors from 63.37% up to 69.81%). This result contributes to designing and optimizing efficient polymers.
期刊介绍：
Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
