Enhanced wastewater treatment using biochar-supported layered-double-hydroxide composites

IF 13.2 1区 工程技术 Q1 ENGINEERING, CHEMICAL Chemical Engineering Journal Pub Date : 2025-01-27 DOI:10.1016/j.cej.2025.159969
Ao Huang, Nan Zhang, Qian-Bin Wang, Bo-Han Zhao, Rui-Bao Zhang, Ming Cheng, Chen Shi, Xiao-Di Hao
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Abstract

With industrialization advances, the volume of wastewater produced has increased considerably. In recent years, biochar-loaded layered double hydroxides (BC–LDHs) have emerged as a low-cost, sustainable composite material with promising applications in wastewater treatment. Improving the adsorption performance of materials is a central focus in the field of wastewater treatment. Currently, most studies emphasize the adsorption applications of BC–LDHs. However, this study not only discusses existing mainstream methods for enhancing adsorption performance but also shifts the focus from BC modification to LDH synthesis. Building on this, new potential modification methods are proposed to achieve improved adsorption performance. One such method involves obtaining new anion-intercalated BC–LDHs through ion exchange. Another approach is to synthesize BC–LDHs via electrodeposition, which involves using an LDH as the working electrode and then loading BC onto it or using BC as one of the electrodes with a mixed metal salt solution as the electrolyte. Different synthesis methods often result in distinct material properties. The electrodeposition method is used to synthesize BC–LDHs with the aim of achieving material modification. In addition, the factors influencing BC–LDHs are analyzed. Through meta-analysis, the study identifies notable factors affecting the adsorption properties of pollutants, including different synthesis methods, the specific surface area of BC–LDHs, adsorbent dosage, and initial pH. This analysis offers a more intuitive foundation for guiding subsequent research by focusing on these critical factors. Finally, the main adsorption mechanism of BC–LDHs is summarized, and future research directions for BC–LDHs are proposed.

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生物炭负载层状双氢氧化物复合材料强化废水处理
随着工业化的推进,废水产生量大幅增加。近年来,生物炭负载层状双氢氧化物(BC-LDHs)作为一种低成本、可持续的复合材料在污水处理中具有广阔的应用前景。提高材料的吸附性能一直是污水处理领域的研究热点。目前,大多数研究都强调BC-LDHs的吸附应用。然而,本研究不仅讨论了现有主流的提高吸附性能的方法,而且将重点从BC改性转移到LDH合成。在此基础上,提出了新的改性方法来提高吸附性能。其中一种方法是通过离子交换获得新的阴离子插层BC-LDHs。另一种方法是通过电沉积法合成BC - ldhs,其中包括使用LDH作为工作电极,然后将BC加载到其上或使用BC作为其中一个电极,混合金属盐溶液作为电解质。不同的合成方法往往导致不同的材料性质。采用电沉积法合成BC-LDHs,目的是实现材料改性。此外,还分析了bc - ldl的影响因素。通过meta分析,本研究发现了不同合成方法、BC-LDHs比表面积、吸附剂用量、初始ph等影响污染物吸附性能的显著因素,为重点研究这些关键因素,指导后续研究提供了更直观的基础。最后总结了BC-LDHs的主要吸附机理,并对BC-LDHs今后的研究方向进行了展望。
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来源期刊
Chemical Engineering Journal
Chemical Engineering Journal 工程技术-工程:化工
CiteScore
21.70
自引率
9.30%
发文量
6781
审稿时长
2.4 months
期刊介绍: The Chemical Engineering Journal is an international research journal that invites contributions of original and novel fundamental research. It aims to provide an international platform for presenting original fundamental research, interpretative reviews, and discussions on new developments in chemical engineering. The journal welcomes papers that describe novel theory and its practical application, as well as those that demonstrate the transfer of techniques from other disciplines. It also welcomes reports on carefully conducted experimental work that is soundly interpreted. The main focus of the journal is on original and rigorous research results that have broad significance. The Catalysis section within the Chemical Engineering Journal focuses specifically on Experimental and Theoretical studies in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. These studies have industrial impact on various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection.
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