Unlocking Interpretable Prediction of Battery Random Discharge Capacity With Domain Adaptative Physics Constraint

IF 26 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Advanced Energy Materials Pub Date : 2025-01-28 DOI:10.1002/aenm.202405506
Yunhong Che, Jia Guo, Yusheng Zheng, Daniel-Ioan Stroe, Wenxue Liu, Xiaosong Hu, Remus Teodorescu
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Abstract

Tracking the battery discharge capacity is significant, yet challenging due to complicated degradation patterns as well as varying or even random usage scenarios. This work proposes a physics-constrained domain adaptation framework to predict the capacities during random discharge with non-destructive mechanism diagnosis using early or random discharging information. By imposing the impedance as physical constraints in a domain adaptative layer, the interpretability and generalization of the model can be improved as the physics-constrained layer provides physical insights into the battery mechanism characteristics, enabling onboard and non-destructive diagnosis without complex tests. The learned impedances in the physics-constrained layer are well-fitted to the real ones, suggesting accurate physical insights and, therefore, good interpretability of the trained model. Furthermore, apart from capacity prediction, the aging mechanisms of the cell can be interpreted through the learned physics from this deep learning framework without impedance measurement. Such interpretation has also been validated experimentally through post-mortem analysis. This work provides an example of grey-box modeling of complex dynamic systems where deep learning models can provide certain physical details to increase the model's interpretability.

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基于领域自适应物理约束的电池随机放电容量可解释性预测
跟踪电池放电容量非常重要,但由于复杂的退化模式以及变化甚至随机的使用场景,因此具有挑战性。本研究提出了一个物理约束域自适应框架,利用早期或随机放电信息预测随机放电期间的容量和非破坏性机制诊断。通过在域自适应层中施加阻抗作为物理约束,可以提高模型的可解释性和泛化性,因为物理约束层提供了对电池机制特性的物理见解,无需复杂的测试即可实现板载和非破坏性诊断。在物理约束层中学习到的阻抗与实际阻抗很好地拟合,这表明了准确的物理洞察力,因此,训练模型具有良好的可解释性。此外,除了容量预测外,细胞的老化机制可以通过从该深度学习框架中学习的物理来解释,而无需阻抗测量。这种解释也通过死后分析得到了实验验证。这项工作为复杂动态系统的灰盒建模提供了一个例子,其中深度学习模型可以提供某些物理细节以增加模型的可解释性。
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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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