Development of a miniaturized current type H2 gas sensor based on Nafion and Pt-Pd/C sensing electrode

IF 3.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2025-05-01 Epub Date: 2025-02-01 DOI:10.1016/j.snb.2025.137366
Hongcan Zhang, Lingchu Huang, Yuanlin Li, Yongshun Liu, Xishuang Liang, Geyu Lu
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Abstract

In this manuscript, a miniaturized current type gas sensor based on the membrane electrode assemble (MEA) composed of Nafion and Pt-Pd/C sensing electrode has been developed to realize the effective detection of H2 at room temperature. The newly designed sensor is significantly smaller than current common gas sensors, and the structure of the sensor and test fixture has been redesigned. The miniature sensor is easy to carry, install and apply to other devices on a daily basis, the manufacturing cost is greatly reduced, and precious metals can be used in the selection of gas-sensitive materials. In the experiment, we used Pt and Pd bimetallic stretcher loaded on carbon as sensing material, both noble metals are sensitive to H2 and have high catalytic activity, which enables efficient detection of H2 gas. The sensor could detect H2 at levels as low as 3 ppm with a −0.163 nA response and had a good linear relationship in range of 30–6000 ppm H2. In addition, this amperometric H2 sensor displayed fast response-recovery rate as well as excellent selectivity and stability. Within the explosive limits of H2, our sensors enable fast and accurate detection. Such a miniaturized device has a good application prospect due to its advantages.
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基于Nafion和Pt-Pd/C传感电极的小型电流型H2气体传感器的研制
本文研制了一种基于Nafion和Pt-Pd/C传感电极组成的膜电极组件(MEA)的小型化电流型气体传感器,实现了室温下氢气的有效检测。新设计的传感器明显小于目前常见的气体传感器,并对传感器和测试夹具的结构进行了重新设计。微型传感器便于携带、安装和日常应用于其他设备,制造成本大大降低,并且在气敏材料的选择上可以使用贵金属。在实验中,我们使用负载在碳上的Pt和Pd双金属拉伸器作为传感材料,这两种贵金属对H2都很敏感,具有很高的催化活性,可以高效检测H2气体。该传感器可以检测低至3 ppm的H2, nA响应为-0.163,在30-6000 ppm的H2范围内具有良好的线性关系。此外,该安培式氢气传感器具有快速的响应恢复速度、良好的选择性和稳定性。在氢气的爆炸范围内,我们的传感器能够快速准确地检测。这种小型化装置由于其自身的优点,具有良好的应用前景。
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来源期刊
Sensors and Actuators B: Chemical
Sensors and Actuators B: Chemical 工程技术-电化学
CiteScore
14.60
自引率
11.90%
发文量
1776
审稿时长
3.2 months
期刊介绍: Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.
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