A non-enzymatic highly stable electrochemical sensing platform based on allylamine capped copper nanoparticles for the detection of the soil nitrate content

IF 3.6 3区化学 Q2 CHEMISTRY, ANALYTICAL Analyst Pub Date : 2025-02-03 DOI:10.1039/d4an01345j

Bimalendu Mukherjee, Mukti Mandal, Raghavv Raghavender Suresh, Shantanu Kar, Binaya Kumar Parida, Somsubhra Chakraborty, Gorachand Dutta

{"title":"A non-enzymatic highly stable electrochemical sensing platform based on allylamine capped copper nanoparticles for the detection of the soil nitrate content","authors":"Bimalendu Mukherjee, Mukti Mandal, Raghavv Raghavender Suresh, Shantanu Kar, Binaya Kumar Parida, Somsubhra Chakraborty, Gorachand Dutta","doi":"10.1039/d4an01345j","DOIUrl":null,"url":null,"abstract":"Nitrate (NO3−) ion contamination of water is a major issue that affects many parts of the world due to excessive usage of nitrogen containing fertilizers in the soil. Hence, quantification of NO3− ions in the soil is of utmost importance. In the present research work, we have developed an efficient and highly stable non-enzymatic electrochemical sensor for NO3− ion detection based on allylamine capped copper nanoparticles (Alym@CuNPs) decorated on exfoliated multi-walled carbon nanotubes (Exf-CNTs). Herein, we have addressed the sensor surface storage stability issue of copper nanoparticle based electrochemical sensors for the first time and confirmed the superior storage stability of the Alym@CuNPs modified glassy carbon electrode (GCE) over uncapped copper nanoparticles (uCuNPs) and electrodeposited copper nanoparticles (eCuNPs) modified GCEs. In comparison to the bare GCE, Exf-CNT/GCE and Alym@CuNPs/Exf-CNT/GCE, the proposed Alym@CuNPs-Nafion (NF)/Exf-CNT/GCE demonstrated enhanced catalytic activity towards the electro-reduction of NO3− ions (pH = 2) under optimal experimental conditions, with a considerable increase in cathodic peak currents. Along with that, no inert gas was purged into the electrolyte medium prior to the detection of NO3− ions which makes the sensor more reliable under real environmental conditions. The sensor displayed broad linear ranges from 10 to 1000 μM (R2 = 0.997), with a limit of detection (LOD) of 5.28 μM (n = 3) for NO3− ion detection. The sensor surface shows excellent storage stability even up to 45 days with 97.8% retention in current value which is much higher compared to the previously reported works. Additionally, the sensor surface shows promising reproducibility and repeatability results with RSD values of 1.78% and 0.91%, respectively. Moreover, the proposed sensor is successfully utilized to detect NO3− ions in real soil samples.","PeriodicalId":63,"journal":{"name":"Analyst","volume":"26 1","pages":""},"PeriodicalIF":3.6000,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analyst","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4an01345j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Nitrate (NO₃⁻) ion contamination of water is a major issue that affects many parts of the world due to excessive usage of nitrogen containing fertilizers in the soil. Hence, quantification of NO₃⁻ ions in the soil is of utmost importance. In the present research work, we have developed an efficient and highly stable non-enzymatic electrochemical sensor for NO₃⁻ ion detection based on allylamine capped copper nanoparticles (Alym@CuNPs) decorated on exfoliated multi-walled carbon nanotubes (Exf-CNTs). Herein, we have addressed the sensor surface storage stability issue of copper nanoparticle based electrochemical sensors for the first time and confirmed the superior storage stability of the Alym@CuNPs modified glassy carbon electrode (GCE) over uncapped copper nanoparticles (uCuNPs) and electrodeposited copper nanoparticles (eCuNPs) modified GCEs. In comparison to the bare GCE, Exf-CNT/GCE and Alym@CuNPs/Exf-CNT/GCE, the proposed Alym@CuNPs-Nafion (NF)/Exf-CNT/GCE demonstrated enhanced catalytic activity towards the electro-reduction of NO₃⁻ ions (pH = 2) under optimal experimental conditions, with a considerable increase in cathodic peak currents. Along with that, no inert gas was purged into the electrolyte medium prior to the detection of NO₃⁻ ions which makes the sensor more reliable under real environmental conditions. The sensor displayed broad linear ranges from 10 to 1000 μM (R² = 0.997), with a limit of detection (LOD) of 5.28 μM (n = 3) for NO₃⁻ ion detection. The sensor surface shows excellent storage stability even up to 45 days with 97.8% retention in current value which is much higher compared to the previously reported works. Additionally, the sensor surface shows promising reproducibility and repeatability results with RSD values of 1.78% and 0.91%, respectively. Moreover, the proposed sensor is successfully utilized to detect NO₃⁻ ions in real soil samples.

Abstract Image