Kang Zhang, Luting Feng, Yujie Jin, Jiyong Liu, Simon Duttwyler
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引用次数: 0
Abstract
A σ,π-bis(copper) actylide complex, (CB11H11-12-C≡C)Cu2(PiPr3)3 (2), enables the formation of regioselective 1,4-disubstituted 1,2,3-triazoles containing monocarborane anion [CB11H12]- via CuAAC with organic azides under mild conditions. This mothod achieves 1,2,3-triazolylated monocarboranes (3) in up to 97% yield, including a luminescent compound with optoelectronic potential.
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