Thermal radiation analysis of a broadband solar energy-capturing absorber using Ti and GaAs

IF 3.3 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2025-02-04 DOI:10.1039/D4DT03202K
Yifan Xiao, Can Ma, Tangyou Sun, Qianju Song, Liang Bian, Zao Yi, Zhiqiang Hao, Chaojun Tang, Pinghui Wu and Qingdong Zeng
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Abstract

This study employed a time-domain finite-difference (FDTD) approach to design an efficient solar energy-capturing absorber consisting of a high melting point metal (Ti) and a semiconductor (GaAs). The structure generated cavity resonance (CR) and surface plasmon resonance (SPR), leading to extremely high absorption across different wavelength bands. The structure exhibited >90% absorption over a wide wavelength range (280–3000 nm). It achieved an average absorption efficiency of 97.0% in the wavelength range from 280 nm to 3000 nm at an air mass of 1.5 (AM1.5). The structure showed insensitivity to the angle of incidence, maintaining stable absorption of over 94% for angles of incidence ranging from 0° to 60°. The structure could also operate at 1400 K, with thermal radiation efficiencies of up to 98.2%. As the operating temperature increased from 600 K to 1400 K (with a temperature gradient of 200 K), the thermal radiation efficiency of the structure remained above 98% at all times. Based on the excellent radiation and absorption properties of this absorber, it holds promising application in the fields of solar energy absorption and thermal emission.

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Ti和GaAs宽带太阳能捕获吸收体的热辐射分析
本文采用时域有限差分(FDTD)方法设计了由高熔点金属(Ti)和半导体(GaAs)组成的高效太阳能捕获吸收器。该结构可产生腔共振(CR)和表面等离子体共振(SPR),在不同波长波段实现极高的吸收。在较宽的波长范围内(280-3000 nm),该结构具有90%以上的吸收率。在空气质量为1.5 (AM 1.5)时,该结构在280 ~ 3000 nm波长范围内的平均吸收效率为97.0%。该结构对入射角不敏感,在0°到60°的入射角范围内,吸收稳定在94%以上。该结构也可以在1400k下工作,热辐射效率高达98.2%。当工作温度从600 K上升到1400 K(温度梯度为200 K)时,结构的热辐射效率始终保持在98%以上。基于该吸收体优异的辐射吸收性能,在太阳能吸收和热发射领域具有广阔的应用前景。
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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