Cu-catalyzed Bilateral Linkage of Sulfenamides for the Construction of Cyclic Sulfilimines

IF 2.5 3区 化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2025-02-04 DOI:10.1002/ejoc.202401467
Xinyu Zhang, Rutian Sun, Daming Zeng, Ming Wang, Xuefeng Jiang
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引用次数: 0

Abstract

A CuI-catalyzed bilateral linkage of S-phenethyl-sulfenamides with cyclic diaryliodonium salts was developed for the one-step construction of cyclic sulfilimines. The challenging cyclic sulfoximines can be efficiently obtained via subsequent oxidation. Photophysical properties and DFT calculations reveal that cyclic sulfoximines, compared to cyclic sulfilimines and sulfones, exhibit larger Stokes shifts and reduced HOMO-LUMO orbital overlap.
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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