Microrotors with Tunable Trajectory Curvatures Driven by Chemical and Photochemical Dual Engines

IF 8.7 1区 化学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Materials Letters Pub Date : 2025-01-23 DOI:10.1021/acsmaterialslett.4c02111
Ruitong Zhu, Donghao Cui, Dezhou Cao, Zuyao Yan, Shifang Duan and Wei Wang*, 
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Abstract

A major challenge in developing smart micromachines that can mimic natural microorganisms is their ability to adapt to changing environments. This study presents a matchstick-shaped microrotor consisting of a TiO2 head and a SiO2 tail, with one side coated by PtO. The TiO2 head provides photochemical propulsion under UV light, while the PtO coating provides chemical propulsion in H2O2. The microrotor rotates because of its asymmetric structure and uneven propulsion forces. Notably, under stronger UV light, the rotor orbits in tighter circles as the photochemical engine counteracts the chemical engine, with the two engines located on opposite sides of the center of mass. Additionally, microrotors with shorter SiO2 tails moved in smaller circles and were more sensitive to changes in light intensity.

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由化学和光化学双引擎驱动的轨迹曲率可调的微转子
开发能够模仿自然微生物的智能微机器的主要挑战是它们适应不断变化的环境的能力。本研究提出了一种火柴棒状的微转子,由TiO2头部和SiO2尾部组成,其一侧涂覆PtO。TiO2头在紫外光下提供光化学推进,而PtO涂层在H2O2中提供化学推进。微转子由于其结构不对称和推进力不均匀而旋转。值得注意的是,在更强的紫外光下,由于光化学发动机与化学发动机相互抵消,转子的轨道绕得更紧,两个发动机位于质心的两侧。此外,二氧化硅尾部较短的微转子运动圈较小,对光强的变化更敏感。
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来源期刊
ACS Materials Letters
ACS Materials Letters MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
14.60
自引率
3.50%
发文量
261
期刊介绍: ACS Materials Letters is a journal that publishes high-quality and urgent papers at the forefront of fundamental and applied research in the field of materials science. It aims to bridge the gap between materials and other disciplines such as chemistry, engineering, and biology. The journal encourages multidisciplinary and innovative research that addresses global challenges. Papers submitted to ACS Materials Letters should clearly demonstrate the need for rapid disclosure of key results. The journal is interested in various areas including the design, synthesis, characterization, and evaluation of emerging materials, understanding the relationships between structure, property, and performance, as well as developing materials for applications in energy, environment, biomedical, electronics, and catalysis. The journal has a 2-year impact factor of 11.4 and is dedicated to publishing transformative materials research with fast processing times. The editors and staff of ACS Materials Letters actively participate in major scientific conferences and engage closely with readers and authors. The journal also maintains an active presence on social media to provide authors with greater visibility.
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