Xia Li , Yi Li , Huimin Yang , Anjie Liu , Songwei Zhang , Litian Hu
{"title":"Enhancement lubrication effect of a novel thiophosphate as additive of lithium complex grease in comparison to ZDDP","authors":"Xia Li , Yi Li , Huimin Yang , Anjie Liu , Songwei Zhang , Litian Hu","doi":"10.1016/j.triboint.2025.110549","DOIUrl":null,"url":null,"abstract":"<div><div>The demand of high-performance additives suitable for lubricating grease is increasing with the development of high-end equipment. Herein, a novel thiophosphate 3-(O, O- di-nonylphenol di-thiophosphate)-2-methylpropanoic acid (NDMA) was synthesized and added to lithium complex grease as an extreme pressure and anti-wear additive. The physicochemical, rheological, and tribological properties of NDMA were studied and compared with ZDDP. The results indicate that NDMA can improve and enhance oil separation under pressure and dropping point. NDMA showed better shearing resistance, friction reducing, anti-wear and load carrying capability than ZDDP. The lubrication mechanism of NDMA was demonstrated through molecular dynamics simulation. The results indicate that NDMA has strong adsorption capacity on sliding surfaces, promoting the tribo-chemistry reaction between NDMA and iron surfaces.</div></div>","PeriodicalId":23238,"journal":{"name":"Tribology International","volume":"205 ","pages":"Article 110549"},"PeriodicalIF":6.1000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tribology International","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0301679X25000441","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/1/20 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The demand of high-performance additives suitable for lubricating grease is increasing with the development of high-end equipment. Herein, a novel thiophosphate 3-(O, O- di-nonylphenol di-thiophosphate)-2-methylpropanoic acid (NDMA) was synthesized and added to lithium complex grease as an extreme pressure and anti-wear additive. The physicochemical, rheological, and tribological properties of NDMA were studied and compared with ZDDP. The results indicate that NDMA can improve and enhance oil separation under pressure and dropping point. NDMA showed better shearing resistance, friction reducing, anti-wear and load carrying capability than ZDDP. The lubrication mechanism of NDMA was demonstrated through molecular dynamics simulation. The results indicate that NDMA has strong adsorption capacity on sliding surfaces, promoting the tribo-chemistry reaction between NDMA and iron surfaces.
期刊介绍：
Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International.
Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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