Metal species confined in metal-organic frameworks for CO2 hydrogenation: Synthesis, catalytic mechanisms, and future perspectives

IF 15.7 1区 化学 Q1 CHEMISTRY, APPLIED Chinese Journal of Catalysis Pub Date : 2025-01-01 DOI:10.1016/S1872-2067(24)60177-4
Bailing Zhong , Jundie Hu , Xiaogang Yang , Yinying Shu , Yahui Cai , Chang Ming Li , Jiafu Qu
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Abstract

ABSTRACT

Metal-organic frameworks (MOFs) serve as highly effective hosts for ultrasmall metal species, creating advanced nanocatalysts with superior catalytic performance, stability, and selective activity. The synergistic interplay between metal species confined within MOF nanopores and their active sites enhances catalytic efficiency in CO2 hydrogenation reactions. Herein, recent advancements in synthesizing metal-confined MOFs are discussed, along with their applications in catalyzing CO2 conversion through various methods such as photocatalysis, thermal catalysis, and photothermal catalysis. Additionally, we further emphasize the fundamental principles and factors that influence various types of catalytic CO2 hydrogenation reactions, while offering insights into future research directions in this dynamic field.
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来源期刊
Chinese Journal of Catalysis
Chinese Journal of Catalysis 工程技术-工程:化工
CiteScore
25.80
自引率
10.30%
发文量
235
审稿时长
1.2 months
期刊介绍: The journal covers a broad scope, encompassing new trends in catalysis for applications in energy production, environmental protection, and the preparation of materials, petroleum chemicals, and fine chemicals. It explores the scientific foundation for preparing and activating catalysts of commercial interest, emphasizing representative models.The focus includes spectroscopic methods for structural characterization, especially in situ techniques, as well as new theoretical methods with practical impact in catalysis and catalytic reactions.The journal delves into the relationship between homogeneous and heterogeneous catalysis and includes theoretical studies on the structure and reactivity of catalysts.Additionally, contributions on photocatalysis, biocatalysis, surface science, and catalysis-related chemical kinetics are welcomed.
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