Metal species confined in metal-organic frameworks for CO2 hydrogenation: Synthesis, catalytic mechanisms, and future perspectives

IF 17.7 1区 化学 Q1 CHEMISTRY, APPLIED Chinese Journal of Catalysis Pub Date : 2025-01-01 Epub Date: 2025-01-09 DOI:10.1016/S1872-2067(24)60177-4
Bailing Zhong , Jundie Hu , Xiaogang Yang , Yinying Shu , Yahui Cai , Chang Ming Li , Jiafu Qu
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Abstract

ABSTRACT

Metal-organic frameworks (MOFs) serve as highly effective hosts for ultrasmall metal species, creating advanced nanocatalysts with superior catalytic performance, stability, and selective activity. The synergistic interplay between metal species confined within MOF nanopores and their active sites enhances catalytic efficiency in CO2 hydrogenation reactions. Herein, recent advancements in synthesizing metal-confined MOFs are discussed, along with their applications in catalyzing CO2 conversion through various methods such as photocatalysis, thermal catalysis, and photothermal catalysis. Additionally, we further emphasize the fundamental principles and factors that influence various types of catalytic CO2 hydrogenation reactions, while offering insights into future research directions in this dynamic field.
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限制在金属-有机框架中的金属物种用于CO2加氢:合成、催化机制和未来展望
摘要金属有机框架(mof)作为超小型金属的高效载体,创造了具有优异催化性能、稳定性和选择性活性的先进纳米催化剂。限制在MOF纳米孔内的金属及其活性位点之间的协同相互作用提高了CO2加氢反应的催化效率。本文讨论了金属约束mof的合成进展,以及它们在光催化、热催化和光热催化等多种方法催化CO2转化中的应用。此外,我们进一步强调了影响各种类型的催化CO2加氢反应的基本原理和因素,同时对这一动态领域的未来研究方向提出了见解。
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来源期刊
Chinese Journal of Catalysis
Chinese Journal of Catalysis 工程技术-工程:化工
CiteScore
25.80
自引率
10.30%
发文量
235
审稿时长
1.2 months
期刊介绍: The journal covers a broad scope, encompassing new trends in catalysis for applications in energy production, environmental protection, and the preparation of materials, petroleum chemicals, and fine chemicals. It explores the scientific foundation for preparing and activating catalysts of commercial interest, emphasizing representative models.The focus includes spectroscopic methods for structural characterization, especially in situ techniques, as well as new theoretical methods with practical impact in catalysis and catalytic reactions.The journal delves into the relationship between homogeneous and heterogeneous catalysis and includes theoretical studies on the structure and reactivity of catalysts.Additionally, contributions on photocatalysis, biocatalysis, surface science, and catalysis-related chemical kinetics are welcomed.
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