Hydrometallurgy recycling of heavy metals from electroplating sludge: Recent development and challenge

IF 3.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Chemical Engineering Research & Design Pub Date : 2025-02-01 Epub Date: 2024-12-30 DOI:10.1016/j.cherd.2024.12.035
Zhu Suiyi , Lan Xin , Zheng Minglin , Lin Yingzi , Li Siwen , Htet Oo Kaung , Yang Weilu , Qin Wensheng , Jadambaa Temuujin , Yu Yang , Liu Jiancong , Luo Wenjing , Chen Yu
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Abstract

Electroplating sludge contains various heavy metals along with impurities such as iron, aluminum, silicon, and calcium. The hydrometallurgical route offers significant advantages for recovering high-purity heavy metal products from sludge, including sponge, salt, and oxyhydroxides. This paper reviews classical hydrometallurgical processes, such as selective leaching, thermochemical extraction, precipitation, and crystallization. Given the co-dissolution of heavy metals and impurities in acidic or alkaline solutions, the efficient separation of impurities is emphasized to simplify these often complex hydrometallurgical processes. Additionally, this review explores the chemical transformation and separation of impurities into byproducts such as gypsum, anorthite, hematite, giniite, boehmite, and natroalunite. Ultimately, this review provides a theoretical foundation for the effective treatment and resource recovery of industrial electroplating sludge.
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湿法冶金回收电镀污泥中重金属的研究进展与挑战
电镀污泥中含有各种重金属以及铁、铝、硅、钙等杂质。湿法冶金在从污泥中回收高纯度重金属产品方面具有显著的优势,包括海绵、盐和氢氧化物。本文综述了经典的湿法冶金工艺,如选择性浸出、热化学萃取、沉淀和结晶。考虑到重金属和杂质在酸性或碱性溶液中的共溶,强调杂质的有效分离以简化这些通常复杂的湿法冶金过程。此外,本文还探讨了杂质的化学转化和分离为副产品,如石膏、钙长石、赤铁矿、绢云母、薄铝石和钠矾石。为工业电镀污泥的有效处理和资源化利用提供理论依据。
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来源期刊
Chemical Engineering Research & Design
Chemical Engineering Research & Design 工程技术-工程:化工
CiteScore
6.10
自引率
7.70%
发文量
623
审稿时长
42 days
期刊介绍: ChERD aims to be the principal international journal for publication of high quality, original papers in chemical engineering. Papers showing how research results can be used in chemical engineering design, and accounts of experimental or theoretical research work bringing new perspectives to established principles, highlighting unsolved problems or indicating directions for future research, are particularly welcome. Contributions that deal with new developments in plant or processes and that can be given quantitative expression are encouraged. The journal is especially interested in papers that extend the boundaries of traditional chemical engineering.
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