The Use of a Cativa-Type Catalyst for the Self-Reductive Decarbonylation of Long Chain Aliphatic Carboxylic Acids into Noralkanes

IF 3.8 3区 化学 Q2 CHEMISTRY, PHYSICAL ChemCatChem Pub Date : 2024-10-25 DOI:10.1002/cctc.202401370
Prof. Takahide Fukuyama, Mr. Masaya Kaneko, Mr. Takayuki Fukunaga, Prof. Ilhyong Ryu
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Abstract

The one-carbon degradation  of aliphatic carboxylic acids has been studied using a H2IrCl6-Ru(CO)4I2 bimetallic catalyst. Alkanes, RH, have been obtained from the corresponding RCOOH in good to near quantitative yields via a process that is thought to involve (i) a decarbonylation process that involves the formation of alkenes along with CO and H2O, (ii) a water–gas shift (WGS) reaction to give H2 and CO2, and (iii) the hydrogenation of the resulting alkenes.

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来源期刊
ChemCatChem
ChemCatChem 化学-物理化学
CiteScore
8.10
自引率
4.40%
发文量
511
审稿时长
1.3 months
期刊介绍: With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
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