The insight effect of texture components on the recrystallization behavior of MoRe alloy

IF 5.5 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Materials Characterization Pub Date : 2025-02-01 Epub Date: 2024-12-27 DOI:10.1016/j.matchar.2024.114694
Congqing Liu , Jingjing Liao , Jun Wu , Fuen Zhang , Hongling Zhou , An Yan , Yuzhen Jia , Haiming Zhang , Quan Li , Xun Dai , Chao Sun , Baifeng Luan
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Abstract

Molybdenum alloys are promising materials for high-temperature gas-cooled reactor fuel cladding due to their excellent performance at elevated temperatures, favorable mechanical properties, corrosion resistance, and low neutron absorption cross-section. However, their high melting point and inherent hardness require annealing to improve processability. This study investigates the effects of vacuum annealing on the microstructure and texture evolution of rotary swaged MoRe alloys. The as-swaged alloy exhibits a fibrous structure with elongated grains along the axial direction (AD). Annealing at 1200 °C results in a bimodal microstructure, with both deformed and recrystallized grains, indicating a partially recrystallized (PRX) state. Furthermore, annealing at 1300 °C leads to a completely recrystallized (CRX) microstructure. The recrystallization mechanism is primarily driven by subgrains coalescence. The texture of the rotary swaged MoRe alloy is dominated by a strong 〈101〉//AD fiber texture, accompanied by a weaker 〈001〉//AD texture. After recrystallization, the intensity of the <101>//AD texture decreases, while the <001>//AD texture becomes more prominent. These texture changes suggest that the <001>//AD texture promotes recrystallization, whereas the <101>//AD texture hinders it. The evolution of the recrystallization texture is attributed to the preferential growth of <001>//AD grains and stress-driven grain rotation. These findings provide valuable insights for optimizing the heat treatment process of rotary swaged MoRe alloys.
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织构成分对MoRe合金再结晶行为的影响
钼合金具有优异的高温性能、良好的力学性能、耐腐蚀性能和较低的中子吸收截面,是高温气冷堆燃料包壳材料的理想材料。然而,它们的高熔点和固有硬度需要退火来提高加工性。研究了真空退火对旋转锻压MoRe合金组织和织构演变的影响。锻压后的合金呈现出沿轴向晶粒拉长的纤维组织。在1200℃下退火后,合金的微观结构为双峰型,晶粒同时变形和再结晶,表明合金处于部分再结晶(PRX)状态。此外,在1300℃下退火导致完全再结晶(CRX)微观结构。再结晶机制主要由亚晶合并驱动。旋锻MoRe合金的织构以< 101 > //AD的强纤维织构为主,同时伴有较弱的< 001 > //AD的织构。再结晶后,<101>;//AD织构强度减小,而<;001>;//AD织构更加突出。这些织构变化表明<;001>;//AD织构促进再结晶,而<;101>;//AD织构阻碍再结晶。再结晶织构的演化与<;001>;//AD晶粒优先生长和应力驱动的晶粒旋转有关。这些发现为优化旋转锻压MoRe合金的热处理工艺提供了有价值的见解。
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来源期刊
Materials Characterization
Materials Characterization 工程技术-材料科学:表征与测试
CiteScore
7.60
自引率
8.50%
发文量
746
审稿时长
36 days
期刊介绍: Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials. The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal. The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include: Metals & Alloys Ceramics Nanomaterials Biomedical materials Optical materials Composites Natural Materials.
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