Corrosion performance of Al-6061 alloy after high-pressure torsion processing

Abstract

The corrosion behavior of a commercial Al-6061 alloy was explored in a 3.5 % (wt%) NaCl solution after high-pressure torsion (HPT) processing at room temperature for numbers of revolutions of N = 0, 1/2, 2 and 10 turns. The microstructures revealed by electron backscatter diffraction (EBSD) showed excellent grain refinement from 121 ± 5 to 0.44 ± 0.1 μm after N = 10 turns with a high fraction of high-angle grain boundaries (∼65 %). The results from electrochemical tests demonstrate that HPT processing significantly improves the corrosion resistance and reduces the corrosion rate due to a combination of grain refinement, an increased dislocation density and texture weakening. The corrosion mechanism was not affected by the HPT processing and found to be controlled by charge transfer. The corrosion morphology of the HPT-processed sample taken through N = 10 turns and observed after 14 days of immersion showed a smooth surface except for the presence of some corrosion microcracks around large particles enriched with Zn and Fe elements.