Interchangeable films made from cellulose acetate and different types of carbon nanotubes with humidity sensing capabilities

IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Sustainable Materials and Technologies Pub Date : 2025-04-01 Epub Date: 2025-01-04 DOI:10.1016/j.susmat.2025.e01237
Madalina Elena Bistriceanu , Andreea Laura Chibac-Scutaru , Florin Tudorache , Sufeng Zhang , Sergiu Coseri
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Abstract

This study presents a novel manufacturing technique for cellulose-based/multi-walled carbon nanotube film (CMF), which produces high-performance, flexible humidity sensors with fast reaction sensing in response to the growing need for wearable technology and environmental monitoring. The technique allows for the production of several kinds of sensors by varying the substrates on which the carbon nanotubes are attached. Because of its exceptional intrinsic qualities as well as its ability to produce films, cellulose acetate was chosen as a support for the implementation of this assembly. Furthermore, we have a great deal of structural flexibility with cellulose acetate since it is easily transformed into cellulose and then into carboxyl cellulose by TEMPO-mediated oxidation. Thus, depending on the chemical structure of each type of substrate, this structural diversity will produce sensors with varying sensitivity and functionality. Furthermore, the range of the examined samples has been further extended by the addition of amino groups to the nanotubes by chemical functionalization. The cellulose-based/CNT films exhibit a response time of only 100 s and demonstrate high reversibility, with sample recovery times exceeding 150 s. Considering these promising results, a wide range of application areas, including wearable technology, environmental tracking, and artificial skin, hold great potential for this straightforward manufacturing technique.
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由醋酸纤维素和不同类型的碳纳米管制成的具有湿度传感能力的可互换薄膜
为了满足日益增长的可穿戴技术和环境监测需求,本研究提出了一种基于纤维素/多壁碳纳米管薄膜(CMF)的新型制造技术,用于生产高性能、柔性、快速反应传感的湿度传感器。该技术允许通过改变碳纳米管附着的衬底来生产几种传感器。由于其独特的内在品质以及生产薄膜的能力,选择醋酸纤维素作为实施该组装的支持。此外,醋酸纤维素具有很大的结构灵活性,因为它很容易通过tempo介导的氧化转化为纤维素,然后转化为羧基纤维素。因此,根据每种衬底的化学结构,这种结构多样性将产生具有不同灵敏度和功能的传感器。此外,通过化学官能化将氨基添加到纳米管中,进一步扩展了检测样品的范围。纤维素基/碳纳米管薄膜的响应时间仅为100秒,具有高可逆性,样品恢复时间超过150秒。考虑到这些有希望的结果,广泛的应用领域,包括可穿戴技术,环境跟踪和人造皮肤,为这种简单的制造技术提供了巨大的潜力。
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来源期刊
Sustainable Materials and Technologies
Sustainable Materials and Technologies Energy-Renewable Energy, Sustainability and the Environment
CiteScore
13.40
自引率
4.20%
发文量
158
审稿时长
45 days
期刊介绍: Sustainable Materials and Technologies (SM&T), an international, cross-disciplinary, fully open access journal published by Elsevier, focuses on original full-length research articles and reviews. It covers applied or fundamental science of nano-, micro-, meso-, and macro-scale aspects of materials and technologies for sustainable development. SM&T gives special attention to contributions that bridge the knowledge gap between materials and system designs.
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