Design of long-term ablation protective Zr0.92Ta0.04Si0.04O2 coating via large lattice distortion and limited phase precipitation

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-01 Epub Date: 2025-01-06 DOI:10.1016/j.corsci.2025.112689
Dou Hu , Xiaoxuan Li , Songlin Chen , Yutai Zhang , Zhe Fan , Kefei Yan , Qiangang Fu
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Abstract

Thermally sprayed Zr-Ta-Si-O coatings were investigated to overcome the oxygen blocking limitations of traditionally self-derived porous ZrO2 layer. The individual solid solution of Ta and Si into ZrO2 lattice was respectively found trapped in the rapid phase precipitation and volatile loss, thus exhibiting insufficient ablation property. The as-designed Zr0.92Ta0.04Si0.04O2 coating successfully acquired a near-zero linear recession rate (-0.10 μm/s) after 900 s cyclic ablation (2.4 MW/m2, 15 cycles). Key reasons can be attributed to a continuous sintering promotion and secondary phase precipitation limitation via large lattice distortion, where that of Zr7/8Ta1/16Si1/16O2 lattice exhibits over 200 % increase than Zr7/8Ta1/8O2 lattice.
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基于大晶格畸变和有限相析出的zr0.92 ta0.04 si0.040 o2长期烧蚀防护涂层设计
研究了热喷涂Zr-Ta-Si-O涂层,以克服传统自衍生多孔ZrO2涂层的阻氧局限性。Ta和Si在ZrO2晶格中的固溶体分别被困在快速相析出和挥发损失中,烧蚀性能不足。经过900 s循环烧蚀(2.4 MW/m2, 15次循环),zr0.92 ta0.04 si0.040 o2涂层获得了接近于零的线性衰退速率(-0.10 μm/s)。主要原因是通过较大的晶格畸变来促进烧结,限制二次相析出,其中Zr7/8Ta1/16Si1/16O2晶格的畸变比Zr7/8Ta1/8O2晶格的畸变增加了200 %以上。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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