High performance memristor device from solution processed MnO2 nanowires: Tuning of resistive switching from analog to digital and underlying mechanism

Abstract

This study reports the synthesis of manganese dioxide (MnO₂) nanowires via the hydrothermal method and the fabrication of high-performance memristor devices using solution-processed MnO₂ nanowires. Microstructural characterizations, viz, XRD, SEM, EDAX and XPS of synthesized sample revealed highly crystalline structures of MnO₂ nanowires. As synthesized MnO₂ nanowires, mixed in different weight percentages with poly(methyl methacrylate) (PMMA) solution were deposited on Al electrode to form thin film memristor devices. Resistive switching with both analog and digital behaviors have been realized in Al/MnO₂-PMMA/Al device by controlling the weight percentage (wt %) of MnO₂ in the composite. When the MnO₂ wt % in the composite was low (PMMA: MnO₂ = 1:1), the device exhibited analog type switching, while, the higher concentration of MnO₂ produced digital types of switching. The On/Off current ratio of the device increased gradually with increase in MnO₂ wt %, reaching the highest switching ratio, ca. 10⁶ and excellent endurance (>10⁴ s) for PMMA:MnO₂ = 1:8. Temperature dependent charge transport behavior and impedance spectroscopy was further carried out to explain the underlying resistive switching mechanism of the device.