The hybrid lamella-cylinder structure self-assembled from AB-type multiblock copolymer

IF 3.1 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemical Physics Letters Pub Date : 2025-01-12 DOI:10.1016/j.cplett.2025.141878
Bin Zhao , Tingting Liu , Pengtao Zou , Huaqiu Liang , Qinyi Shi , Xiao Yang , Chao Wang
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Abstract

Block copolymers have attracted extensive attention because they can self-assemble into various nano-sized structures. However, the hybrid structures self-assembled from AB-type block copolymers are very limited, wherein the same chemical composition can self-assemble into different geometric structures. Inspired by the theoretical prediction that A1B1A2B2 tetrablock copolymer can self-assemble into lamella-sphere (LS) structure, the A1B1A2(B2)m (m = 1, 2) copolymer was proposed to facilitate the formation of hybrid lamella-cylinder (LC) nanostructure in this paper. Through the calculation of self-consistent field theory, it has been demonstrated that A1B1A2(B2)2 is capable of self-assembly into hybrid LC structure, while the A1B1A2B2 does not exhibit the ability to form such structures.

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由ab型多嵌段共聚物自组装而成的杂化片柱结构
嵌段共聚物因其可以自组装成各种纳米级结构而受到广泛关注。然而,由ab型嵌段共聚物自组装的杂化结构非常有限,其中相同的化学成分可以自组装成不同的几何结构。受理论预测A1B1A2B2四嵌段共聚物可以自组装成片层-球(LS)结构的启发,本文提出了A1B1A2(B2)m (m = 1,2)共聚物,以促进混合片层-柱(LC)纳米结构的形成。通过自一致场论的计算,证明了A1B1A2(B2)2具有自组装成杂化LC结构的能力,而A1B1A2B2不具备形成这种结构的能力。
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来源期刊
Chemical Physics Letters
Chemical Physics Letters 化学-物理:原子、分子和化学物理
CiteScore
5.70
自引率
3.60%
发文量
798
审稿时长
33 days
期刊介绍: Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage. Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.
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Editorial Board Graphical abstract TOC Contents continued Graphical abstract TOC Spectral origins of frontier-orbital inversions in atoms and molecules
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