Bi-directional evolution of graphenic vacancy structure in oxygen plasma treatment

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Tribology International Pub Date : 2025-04-01 Epub Date: 2025-01-13 DOI:10.1016/j.triboint.2025.110529
Yinong Chen , Shuyu Fan , Shu Xiao , Hu Zhang , Yi Wu , Jing Wu , Guoliang Tang , Fenghua Su , Paul K. Chu
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Abstract

The phenomenon of friction increase in graphenic materials during prolonged treatment in an oxygen plasma environment has been widely recognized. In this study, we report a possible oxidation state that leads to decreased friction during oxygen plasma treatment of graphenic materials through molecular simulations. We also propose a simple, clean, and efficient method to control the reverse structural evolution for controlled oxidation. Experimental applications demonstrated a 30.6 % reduction in friction and a 130.1 % increase in friction for short and long oxygen plasma treatments, respectively, compared to the initial graphenic vacancy structure. These findings contribute to an increased understanding of the response and modulation of graphenic coatings in oxygen plasma environments.
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氧等离子体处理中石墨空位结构的双向演化
石墨材料在氧等离子体环境中长时间处理时摩擦增加的现象已被广泛认识。在这项研究中,我们通过分子模拟报告了一种可能的氧化状态,这种氧化状态导致石墨材料在氧等离子体处理过程中摩擦减少。我们还提出了一种简单、清洁、有效的方法来控制氧化的反向结构演变。实验应用表明,与初始石墨空位结构相比,短时间和长时间氧等离子体处理的摩擦分别减少了30.6% %和130.1 %。这些发现有助于增加对石墨涂层在氧等离子体环境中的响应和调制的理解。
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来源期刊
Tribology International
Tribology International 工程技术-工程:机械
CiteScore
10.10
自引率
16.10%
发文量
627
审稿时长
35 days
期刊介绍: Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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