Improved mechanical and tribological properties of epoxy resin with new hyperbranched polysiloxane grafted MXene/Ag hybrids

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Tribology International Pub Date : 2025-01-06 DOI:10.1016/j.triboint.2025.110515
Zhou Lan , Zhengyan Chen , Maoyu Zhang , Wei Huang , Du Ding , Baoli Fan , Hongxia Yan , Yanling Jin , Zhenfeng Sun , Fang Ren , Penggang Ren
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Abstract

In this study, different MXene/Ag hybrids were synthesized via an in-situ reduction method, followed by a “one-pot” strategy to design hydroxyl-terminated hyperbranched polysiloxane (HBPSi-OH) as a “bridging” structure to enhance the compatibility between MXene/Ag and epoxy resin (EP), forming the HMA/EP composite. Benefiting from the rigidity-flexibility synergistic effect between MXene/Ag and HBPSi-OH, 0.6 wt% HMA-2/EP composite exhibited the highest impact strength (35.3 kJ/m2) and flexural strength (146.3 MPa). Meanwhile, its average coefficient of friction (COF) and volume wear rate were significantly reduced by 32.8 % and 96.0 %, respectively, compared to pure EP resin. This work offers valuable insights for advancing high-performance polymer composites in the field of tribology.
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新型超支化聚硅氧烷接枝MXene/Ag杂化物改善环氧树脂的力学和摩擦学性能
本研究通过原位还原法合成了不同的MXene/Ag杂化物,然后采用“一锅”策略设计端羟基超支化聚硅氧烷(HBPSi-OH)作为“桥接”结构,增强MXene/Ag与环氧树脂(EP)之间的相容性,形成HMA/EP复合材料。得益于MXene/Ag和HBPSi-OH之间的刚柔协同效应,0.6 wt% HMA-2/EP复合材料具有最高的冲击强度(35.3 kJ/m2)和抗弯强度(146.3 MPa)。与纯EP树脂相比,其平均摩擦系数(COF)和体积磨损率分别显著降低32.8% %和96.0 %。这项工作为推动高性能聚合物复合材料在摩擦学领域的发展提供了有价值的见解。
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来源期刊
Tribology International
Tribology International 工程技术-工程:机械
CiteScore
10.10
自引率
16.10%
发文量
627
审稿时长
35 days
期刊介绍: Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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