Sodium Alginate-chitosan-starch based glue formulation for sealing biopolymer films

Next Materials Pub Date : 2025-04-01 Epub Date: 2025-01-31 DOI:10.1016/j.nxmate.2025.100507
Sazzadur Rahman , Achyut Konwar , Shalini Gurumayam , Jagat Chandra Borah , Devasish Chowdhury
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Abstract

Biopolymers are potential materials that will eventually replace petroleum-based polymers in various applications, including packaging applications. One of the systems that will be pre-requisitely required is the sealing of biopolymer. Conventional sealing techniques, viz. heat sealing and chemical adhesive, are not suitable for sealing biopolymers. In this work, we have demonstrated the formulation of biopolymer-based glue, which is effective in sealing biopolymers. The formulation includes a rice biopolymer-based composite material with chitosan and sodium alginate and, followed by cross-linking with a natural base (pH∼ 12). The developed glue formulation is effective in joining the litho paper, cotton, and guar gum-chitosan cross-linked biopolymer film (GG-CH-C). The lap shear strength of the prepared glue formulation is maximum for the substrate sodium alginate-chitosan cross-linked biopolymer film. In the presence of high humidity (100 % RH), the lap shear strength of the prepared glue formulation decreases; however, it was still measurable and found to be (2.99 ± 0.34) MPa. A plausible mechanism is discussed to explain the chemical interactions between the prepared glue formulation and the biopolymer film substrates. The cytotoxicity of the prepared glue is tested against CC1 hepatocytes. Hence, rice-biopolymer-based composite is an excellent glue material that is found to be effective in joining two biopolymeric surfaces.
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海藻酸钠-壳聚糖-淀粉基生物聚合物薄膜密封胶配方
生物聚合物是一种潜在的材料,最终将在各种应用中取代石油基聚合物,包括包装应用。其中一个必不可少的系统是生物聚合物的密封。传统的密封技术,即热密封和化学粘合剂,不适合密封生物聚合物。在这项工作中,我们已经证明了生物聚合物基胶水的配方,这是有效的密封生物聚合物。该配方包括一种大米生物聚合物基复合材料,含有壳聚糖和海藻酸钠,然后与天然碱(pH ~ 12)交联。所研制的胶水配方能有效地粘合光刻纸、棉花和瓜尔胶-壳聚糖交联生物聚合物膜(GG-CH-C)。以海藻酸钠-壳聚糖交联生物聚合物薄膜为底物,所制备的胶水配方的搭接剪切强度最大。在高湿条件下(100 % RH),所制胶配方的搭接抗剪强度降低;但仍可测量,结果为(2.99 ± 0.34)MPa。讨论了一种合理的机制来解释所制备的胶水配方与生物聚合物薄膜衬底之间的化学相互作用。制备的胶对CC1肝细胞进行细胞毒性试验。因此,水稻-生物聚合物基复合材料是一种优异的粘合材料,可以有效地连接两个生物聚合物表面。
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