A comprehensive review of layered transition metal oxide cathodes for sodium-ion batteries: The latest advancements and future perspectives

IF 31.6 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Science and Engineering: R: Reports Pub Date : 2024-12-13 DOI:10.1016/j.mser.2024.100902

Pengzhi Li , Tao Yuan , Jian Qiu , Haiying Che , Qianqian Ma , Yuepeng Pang , Zi-Feng Ma , Shiyou Zheng

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引用次数: 0

Abstract

Sodium-ion batteries (SIBs) are emerging as a promising and cost-effective solution for large-scale energy storage systems and smart grids due to the abundant availability of sodium. The cathode materials in SIBs play a crucial role in providing free Na⁺ ions and determining battery potential. Among the various cathode candidates, Na⁺-based layered transition metal oxide cathodes (NTMOs) are considered promising options for practical SIB cathodes, with a high theoretical capacity and energy storage mechanism similar to commercial lithium-ion batteries (LIBs). However, challenges such as structural collapse, particle cracking, oxygen loss, and moisture stability need to be addressed for the full potential of NTMOs in practical SIB applications. This review investigates the underlying factors contributing to these challenges, analyzes the phases and electrochemical performance of NTMOs, and explores various strategies such as preparation technology, morphology control, and interface modulation. The optimization of sodium-ion full-cells composition, including anode selection, electrolyte composition, separator selection, and binders, is also discussed. Overall, this review highlights the potential advantages that NTMOs can offer to the industry by providing fresh perspectives and avenues for future research. Additionally, this comprehensive overview of NTMOs could potentially lead to advancements in the field of SIBs and contribute to the development of more efficient energy storage solutions.

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来源期刊

Materials Science and Engineering: R: Reports 工程技术-材料科学：综合

CiteScore

60.50

自引率

0.30%

发文量

审稿时长

34 days

期刊介绍： Materials Science & Engineering R: Reports is a journal that covers a wide range of topics in the field of materials science and engineering. It publishes both experimental and theoretical research papers, providing background information and critical assessments on various topics. The journal aims to publish high-quality and novel research papers and reviews. The subject areas covered by the journal include Materials Science (General), Electronic Materials, Optical Materials, and Magnetic Materials. In addition to regular issues, the journal also publishes special issues on key themes in the field of materials science, including Energy Materials, Materials for Health, Materials Discovery, Innovation for High Value Manufacturing, and Sustainable Materials development.