{"title":"Response to comment on “Formation of silyl metal hydride, HMnSiH3 and silylidyne, H3ReSiH in the activation of silane by manganese and rhenium atoms”","authors":"Jie Zhao","doi":"10.1016/j.cplett.2024.141789","DOIUrl":null,"url":null,"abstract":"<div><div>This work is in response to the “Comment on ’Formation of silyl metal hydride, HMnSiH<sub>3</sub> and silylidyne, H<sub>3</sub>ReSiH in the activation of silane by manganese and rhenium atoms’”. The experimental results indicate that the assignment of the absorptions at 1804.5 cm<sup>−1</sup> to the Re-H stretching vibration of H<sub>3</sub>ReSiH is more appropriate than to H<sub>3</sub>Re(μ-H)Si, since the Re-H<sub>b</sub> (H<sub>b</sub> = bridging hydrogen) stretching vibration, which is predicted to have considerable IR intensity, was not observed in the experiments.</div></div>","PeriodicalId":273,"journal":{"name":"Chemical Physics Letters","volume":"860 ","pages":"Article 141789"},"PeriodicalIF":3.1000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009261424007310","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This work is in response to the “Comment on ’Formation of silyl metal hydride, HMnSiH3 and silylidyne, H3ReSiH in the activation of silane by manganese and rhenium atoms’”. The experimental results indicate that the assignment of the absorptions at 1804.5 cm−1 to the Re-H stretching vibration of H3ReSiH is more appropriate than to H3Re(μ-H)Si, since the Re-Hb (Hb = bridging hydrogen) stretching vibration, which is predicted to have considerable IR intensity, was not observed in the experiments.
期刊介绍：
Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage.
Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.
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