{"title":"Enhancing sensitivity and selectivity in gas sensors: A novel approach using metal oxide-conducting polymer composites","authors":"A. Al Ojeery , M.A. Farea","doi":"10.1016/j.inoche.2024.113726","DOIUrl":null,"url":null,"abstract":"<div><div>The growing need for effective gas detection technologies has led to significant advancements in the development of gas sensors. This study introduces a novel Poly(o-toluidine) (POT)/Titanium dioxide (TiO<sub>2</sub>) nanocomposite sensor for sulfur dioxide (SO<sub>2</sub>) detection, demonstrating remarkable improvements in sensitivity, selectivity, and response/recovery times. The POT/TiO<sub>2</sub> nanocomposite sensor exhibits a threefold enhancement in sensitivity compared to pure POT, achieving a response of 186 at 50 ppm SO<sub>2</sub> at room temperature, a significant improvement over previous high-temperature-based SO<sub>2</sub> sensors. Additionally, the sensor demonstrates excellent repeatability and stability over 35 days, making it a promising candidate for industrial and environmental monitoring. The synergistic interaction between POT and TiO<sub>2</sub> enhances charge transfer and gas adsorption, resulting in faster and more reliable SO<sub>2</sub> detection and presenting an innovative solution for practical gas sensing applications.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"172 ","pages":"Article 113726"},"PeriodicalIF":4.4000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387700324017167","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The growing need for effective gas detection technologies has led to significant advancements in the development of gas sensors. This study introduces a novel Poly(o-toluidine) (POT)/Titanium dioxide (TiO2) nanocomposite sensor for sulfur dioxide (SO2) detection, demonstrating remarkable improvements in sensitivity, selectivity, and response/recovery times. The POT/TiO2 nanocomposite sensor exhibits a threefold enhancement in sensitivity compared to pure POT, achieving a response of 186 at 50 ppm SO2 at room temperature, a significant improvement over previous high-temperature-based SO2 sensors. Additionally, the sensor demonstrates excellent repeatability and stability over 35 days, making it a promising candidate for industrial and environmental monitoring. The synergistic interaction between POT and TiO2 enhances charge transfer and gas adsorption, resulting in faster and more reliable SO2 detection and presenting an innovative solution for practical gas sensing applications.
期刊介绍:
Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.