Iodine-catalyzed 1-Aryltriazene/CS2 duo for sonochemical synthesis of 3-Sulphenylindoles employing [BMIM(SO3H)][OTf] as recyclable promoting system.

Vinod Jadhav , Athmanand Anchi , Imamhusen Jamadar , Shruti S. Malunavar , Rajesh G. Kalkhambkar , Suraj M. Sutar
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Abstract

Iodine-catalyzed regioselective sulphenylation of various 3-substituted indoles using CS2 as potential tool is demonstrated. An efficient and eco-friendly protocol has been developed to synthesize libraries of 3-sulphenyl indoles by employing CS2 as sulphur coupling-linkage for various 1-aryltriaznes and indoles. Short reaction time, mild reaction conditions, recycle and reuse of ionic liquids (ILs) are the advantages of this methodology. A plausible reaction mechanism to narrate the exploitation of the catalytic and promoting systems is also highlights of this work.

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