Vinod Jadhav , Athmanand Anchi , Imamhusen Jamadar , Shruti S. Malunavar , Rajesh G. Kalkhambkar , Suraj M. Sutar
{"title":"Iodine-catalyzed 1-Aryltriazene/CS2 duo for sonochemical synthesis of 3-Sulphenylindoles employing [BMIM(SO3H)][OTf] as recyclable promoting system.","authors":"Vinod Jadhav , Athmanand Anchi , Imamhusen Jamadar , Shruti S. Malunavar , Rajesh G. Kalkhambkar , Suraj M. Sutar","doi":"10.1016/j.jil.2024.100128","DOIUrl":null,"url":null,"abstract":"<div><div>Iodine-catalyzed regioselective sulphenylation of various 3-substituted indoles using CS<sub>2</sub> as potential tool is demonstrated. An efficient and eco-friendly protocol has been developed to synthesize libraries of 3-sulphenyl indoles by employing CS<sub>2</sub> as sulphur coupling-linkage for various 1-aryltriaznes and indoles. Short reaction time, mild reaction conditions, recycle and reuse of ionic liquids (ILs) are the advantages of this methodology. A plausible reaction mechanism to narrate the exploitation of the catalytic and promoting systems is also highlights of this work.</div></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"5 1","pages":"Article 100128"},"PeriodicalIF":0.0000,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Ionic Liquids","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S277242202400051X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Iodine-catalyzed regioselective sulphenylation of various 3-substituted indoles using CS2 as potential tool is demonstrated. An efficient and eco-friendly protocol has been developed to synthesize libraries of 3-sulphenyl indoles by employing CS2 as sulphur coupling-linkage for various 1-aryltriaznes and indoles. Short reaction time, mild reaction conditions, recycle and reuse of ionic liquids (ILs) are the advantages of this methodology. A plausible reaction mechanism to narrate the exploitation of the catalytic and promoting systems is also highlights of this work.