Fracture behavior of binder jetting 3D printed cemented carbides: Influence of printing direction and testing configuration

IF 4.6 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Refractory Metals & Hard Materials Pub Date : 2025-04-01 Epub Date: 2025-01-24 DOI:10.1016/j.ijrmhm.2025.107069
L. Cabezas , C. Berger , S. Bridy , E. Jiménez-Piqué , P. Moreno , J. Pötschke , L. Llanes
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Abstract

Cemented carbides exhibit an outstanding performance as materials for tools and components. As applications of these materials become more and more challenging, complex tool geometries are often needed to suit the extreme requirements. Within this context, Additive Manufacturing (AM) has emerged as a popular option, as they combine a group of processing techniques involving layer-by-layer printing. In general, AMed samples are expected to exhibit characteristics linked to the layer-by-layer wise shaping route; and hence, a dependence of the mechanical properties on layer directionality may come out. It is then the main objective of this study to investigate, document and understand the fracture behavior of WC-12wt.Co samples fabricated via binder jetting printing (BJT), as a function of layer assemblage orientation. In doing so, specimens corresponding to four combinations of two printing directions and two testing configurations were studied. Use of samples micronotched by means of ultrashort pulsed laser ablation allowed to conclude that, similar to microstructure and hardness, fracture toughness of BJT cemented carbides exhibits an isotropic behavior. However, this is not the case for flexural strength, property for which a strong dependence on the relative orientation of layer assemblage is assessed. In this regard, higher strength and wider data dispersion are attained as loading is applied perpendicular to planes containing layer interfaces, as compared to the parallel case. Similar characteristic strength levels together with relatively lower Weibull modulii, as compared to conventionally manufactured WC-Co grades with similar microstructures, are determined. Extensive and detailed fractographic inspection of broken surfaces allows to conclude that specific location, orientation and distribution of flaws intrinsic to layer interfaces as well as printing route followed, depending on testing configuration, are key factors for defining strength level and dispersion in each case.
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粘结剂喷射3D打印硬质合金断裂行为:打印方向和测试配置的影响
硬质合金作为工具和部件材料具有优异的性能。随着这些材料的应用变得越来越具有挑战性,通常需要复杂的工具几何形状来满足极端要求。在这种背景下,增材制造(AM)已经成为一种流行的选择,因为它们结合了一组涉及逐层打印的加工技术。一般来说,AMed样品有望表现出与逐层成形路线相关的特征;因此,可以得出力学性能与层的方向性的依赖关系。因此,研究、记录和理解WC-12wt的断裂行为是本研究的主要目标。利用粘结剂喷射打印(BJT)制备Co样品,并研究其层装配方向的变化规律。为此,对两种打印方向和两种测试配置的四种组合对应的试样进行了研究。利用超短脉冲激光烧蚀方法对样品进行微切口处理,可以得出结论,与显微组织和硬度相似,BJT硬质合金的断裂韧性表现出各向同性行为。然而,这不是抗弯强度的情况,这是一个很强的依赖于层组合的相对方向的性质进行评估。在这方面,与平行情况相比,当加载垂直于包含层界面的平面时,可以获得更高的强度和更宽的数据分散。与具有相似显微结构的常规制造WC-Co牌号相比,确定了相似的特征强度水平以及相对较低的威布尔模量。对断裂表面进行广泛而详细的断口学检查可以得出结论,根据测试配置,层界面固有缺陷的特定位置、方向和分布以及遵循的打印路线是确定每种情况下强度水平和分散度的关键因素。
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来源期刊
CiteScore
7.00
自引率
13.90%
发文量
236
审稿时长
35 days
期刊介绍: The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.
期刊最新文献
Promoted room-temperature deformability and strength synergy in Nb-Mo-Ta-W-Ti refractory high-entropy alloys via carbon doping Preparation of porous tungsten materials via binder jet 3D printing: Material and process improvement Deep learning-driven automated microstructural quantification in tungsten heavy alloys using U-net segmentation and image processing Effect of powder pre-alloying on the microstructure and mechanical properties of sintered W-4Re alloy Effects of TiC addition on the microstructure and properties of WC-8(Co,Ni)-TiC coarse cemented carbide using the dissolution method with WO3 as the raw material
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