Enhanced corrosion and tribo-corrosion resistance of self-organized nano-multilayer oxynitride coatings on tungsten copper alloy

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-01-25 DOI:10.1016/j.corsci.2025.112740
Ze Zhang , Peng Jin , Yuhe Chen , Teng Fei Zhang , Gobinda Gyawali , Xiaozhe Zhu , Gangfei Li , Shihong Zhang
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Abstract

Surface protective coating is crucial for tungsten-copper alloys to prevent corrosion failure in marine applications. In this work, self-organized nanomultilayer AlCrON coatings with alternating nitrogen-rich and oxygen-rich sublayers were fabricated by arc ion plating technology, whose modulation structure was adjusted by altering substrate-rotation mode. AlCrON deposited with 2D rotation exhibits minimum modulation period and superior protective effect in electrochemical, acidic-salt-spray corrosion and tribo-corrosion conditions. No obvious corrosion was observed on AlCrON coated tungsten-copper alloy after acidic-salt-spray exposure for 180 h. Oxygen doping and nano-multilayer interfaces effectively restrained galvanic corrosion, blocked the intrusion of corrosive media and enhanced the corrosion resistance.
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钨铜合金自组织纳米多层氮化氧涂层的耐腐蚀和耐摩擦腐蚀性能增强
钨铜合金的表面保护涂层是防止腐蚀失效的关键。本文采用电弧离子镀技术制备了富氮富氧交替亚层的自组织AlCrON纳米多层涂层,并通过改变基材旋转模式来调节其调制结构。在电化学、酸盐雾腐蚀和摩擦腐蚀条件下,二维旋转沉积的AlCrON具有最短的调制周期和较好的保护效果。酸盐雾处理180 h后,AlCrON涂层钨铜合金无明显腐蚀。氧掺杂和纳米多层界面有效地抑制了电偶腐蚀,阻断了腐蚀介质的侵入,提高了材料的耐蚀性。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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