Microstructure characteristics and oxidation behavior of a dense Si-Cr-Fe-Ti coating with a multi-layer structure on Nb-Si based alloy by slurry sintering

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-01-27 DOI:10.1016/j.corsci.2025.112743
Weiping Zhang , Yanqiang Qiao , Xiping Guo , Longfei Li , Xi Nan
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Abstract

A dense and multilayered Si-Cr-Fe-Ti coating was prepared on Nb-Si based alloy by slurry sintering. The oxidation behavior of the coating at 1250, 1350 and 1450 ℃ were systematically investigated. The coating exhibits good oxidation resistance at high temperatures, forming dense and multi-layer scales after oxidation at 1250 ℃∼1350 ℃, while forming a dense glassy silica scale at 1450 ℃. The addition of a certain amount of Ti and Fe is beneficial for the formation and stability of the Cr2TiO5 middle layer, thus effectively inhibiting the further oxidation of Cr2O3 to volatile CrO3.
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Nb-Si基合金浆料烧结多层致密Si-Cr-Fe-Ti涂层的组织特征及氧化行为
采用浆料烧结技术在铌硅基合金表面制备了致密的多层Si-Cr-Fe-Ti涂层。系统地研究了涂层在1250、1350和1450℃下的氧化行为。涂层在高温下表现出良好的抗氧化性,在1250℃~ 1350℃氧化后形成致密的多层鳞片,在1450℃氧化后形成致密的玻璃状二氧化硅鳞片。一定量的Ti和Fe的加入有利于Cr2TiO5中间层的形成和稳定,从而有效抑制Cr2O3进一步氧化为易挥发的CrO3。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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