Femtosecond laser-induced micro/nanostructures facilitated multiple passivation and long-term anti-corrosion property of laser powder bed fused Ti-6Al-4V alloy

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-01-30 DOI:10.1016/j.corsci.2025.112757
Jinpeng Fang , Lai-Chang Zhang , Nianwei Dai , Ruixiang Liu , Hao Yao , Zhaoxin Lao , Chao Chen , Yachao Zhang , Sizhu Wu
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Abstract

The formation of non-equilibrium phases and microstructural defects reduces the passivation performance and corrosion resistance of laser powder bed fusion (LPBF) produced Ti-6Al-4V alloy, threatening its safe service as important components. This work aims to enhance the corrosion resistance of LPBF-produced Ti-6Al-4V alloy through femtosecond laser surface processing (FLSP). FLSP at lower powers (<300 mW) or higher powers (>400 mW) creates uniform layers of periodic nanostructures and hierarchical micro/nanostructures on the alloy surface. The prolonged exposure to air significantly accelerates the oxidation of Ti2 + to Ti4+ on FLSP-induced micro/nanostructures, resulting in multiple passivation behaviors and remarkable improvement in corrosion resistance.
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飞秒激光诱导的微纳结构有利于激光粉末床熔合Ti-6Al-4V合金的多次钝化和长期防腐性能
非平衡相和显微组织缺陷的形成降低了激光粉末床熔合Ti-6Al-4V合金的钝化性能和耐蚀性,威胁了Ti-6Al-4V合金作为重要部件的安全使用。本工作旨在通过飞秒激光表面处理(FLSP)提高lpbf生产的Ti-6Al-4V合金的耐腐蚀性。低功率(<300 mW)或高功率(>400 mW)的FLSP在合金表面产生均匀的周期性纳米结构层和分层微/纳米结构。长时间暴露于空气中显著加速了flsp诱导的微纳结构上Ti2 +氧化为Ti4+,导致多种钝化行为,耐蚀性显著提高。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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