Effect of low-temperature oxidation on the bonding and combustion characteristics of asphalt rock

IF 6.2 2区 工程技术 Q2 ENERGY & FUELS Journal of The Energy Institute Pub Date : 2025-02-01 Epub Date: 2024-12-06 DOI:10.1016/j.joei.2024.101926
Jiatao Xiang , Xiong Zhang , Han Zhang , Anmin Dong , Shaohui Ren , Shihong Zhang , Jing'ai Shao , Xianhua Wang , Haiping Yang , Hanping Chen
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Abstract

Asphalt rock, characterized by high viscosity and low grade, poses challenges in fuel feeding and is prone to ash deposition and slagging in boilers. Low-temperature oxidation (LTO) is a promising method for modifying and upgrading inferior fuels. In this study, orthogonal experiments were conducted to determine the optimal LTO conditions and assess its effects on the bonding and combustion characteristics of asphalt rock. The results indicate that the optimal LTO conditions are an oxidation temperature of 240 °C, oxidation time of 20 min, and particle size of 1.0–1.4 mm. Under these conditions, the initial bonding temperature (IBT) of asphalt rock increases to 255 °C, a 35 °C improvement over the untreated sample (220 °C) of the control group (CG), while the weight loss ratio (WLR) is 2.52 %. The oxidation temperature has the most significant impact on both IBT and WLR. When subjected to LTO at 240 °C, the asphalt rock exhibits improved combustion characteristics, with better values for DTGmax, DTGmean, ignition temperature (Ti), peak temperature (Tp), ignition index (Di), and comprehensive combustion index (CCI), compared to the CG. However, the burnout temperature (Tb) and burnout index (Db) are slightly lower than those of CG. Furthermore, both the activation energy (Ea) and frequency factor (A) of asphalt rock increase after LTO, suggesting a significant enhancement in its combustion characteristics. Therefore, LTO proves to be an effective and promising method for improving the bonding and combustion characteristics of asphalt rock.

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低温氧化对沥青岩粘结与燃烧特性的影响
沥青岩具有高粘度、低品位的特点,给燃料的进料带来了挑战,在锅炉中容易产生积灰和结渣。低温氧化是一种很有前途的劣质燃料改性和升级方法。本研究通过正交试验确定了最佳LTO条件,并评估了其对沥青岩粘结和燃烧特性的影响。结果表明,氧化温度为240℃,氧化时间为20 min,粒径为1.0 ~ 1.4 mm。在此条件下,沥青岩的初始粘结温度(IBT)提高到255℃,比对照组(CG)未处理样品(220℃)提高35℃,失重率(WLR)为2.52%。氧化温度对IBT和WLR的影响最为显著。在240℃LTO条件下,沥青岩的燃烧特性得到改善,其DTGmax、DTGmean、着火温度(Ti)、峰值温度(Tp)、着火指数(Di)和综合燃烧指数(CCI)均优于CG。但燃尽温度(Tb)和燃尽指数(Db)略低于CG。此外,LTO后沥青岩的活化能Ea和频率因子A均增加,表明其燃烧特性显著增强。因此,LTO被证明是一种有效且有前景的改善沥青岩粘结和燃烧特性的方法。
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来源期刊
Journal of The Energy Institute
Journal of The Energy Institute 工程技术-能源与燃料
CiteScore
10.60
自引率
5.30%
发文量
166
审稿时长
16 days
期刊介绍: The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include: Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies Emissions and environmental pollution control; safety and hazards; Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS; Petroleum engineering and fuel quality, including storage and transport Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems Energy storage The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.
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