{"title":"Organic–inorganic hybrid 4f-π conductors","authors":"Yi-Han Fu , Ying-Fan Tan , Qingyun Wan","doi":"10.1016/j.poly.2024.117383","DOIUrl":null,"url":null,"abstract":"<div><div>Combining 4f-element complexes with highly conductive molecules like TMTSF (tetramethyltetraselenafulvalene) and TCNQ (tetracyanoquinodimethane) enables the preparation of multifunctional organic–inorganic hybrid materials that could demonstrate both electronic conduction and magnetic properties. These materials hold great promise for applications in molecular electronic devices and related fields. However, creating such materials poses a significant challenge due to the need to integrate both conductive and magnetic ions into the assembly networks. This review article presents the origin, development, and recent advancements in this research field. We believe that these organic–inorganic hybrid materials could behave as an intriguing platform for exploring novel types of multifunctional molecular materials and for delving into the fundamental understanding of 4f-π interactions.</div></div>","PeriodicalId":20278,"journal":{"name":"Polyhedron","volume":"268 ","pages":"Article 117383"},"PeriodicalIF":2.4000,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polyhedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S027753872400559X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Combining 4f-element complexes with highly conductive molecules like TMTSF (tetramethyltetraselenafulvalene) and TCNQ (tetracyanoquinodimethane) enables the preparation of multifunctional organic–inorganic hybrid materials that could demonstrate both electronic conduction and magnetic properties. These materials hold great promise for applications in molecular electronic devices and related fields. However, creating such materials poses a significant challenge due to the need to integrate both conductive and magnetic ions into the assembly networks. This review article presents the origin, development, and recent advancements in this research field. We believe that these organic–inorganic hybrid materials could behave as an intriguing platform for exploring novel types of multifunctional molecular materials and for delving into the fundamental understanding of 4f-π interactions.
期刊介绍：
Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry.
Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.
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