Single-Step Hydrothermal Synthesis of HNO3 Exfoliated Graphite/Fe2O3 Composite for Methanol Oxidation in Acidic Media

IF 2.7 4区化学 Q3 CHEMISTRY, PHYSICAL Electrocatalysis Pub Date : 2024-11-26 DOI:10.1007/s12678-024-00917-3

Shan Ahmed Khan, Aqsa Batool, Muhammad Salman

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Abstract

Methanol has potential to replace conventional fuels. But its popularity is hindered by lower kinetics of electrode reactions, lower surface area, CO poisoning of catalysts, and higher cost of platinum-based catalysts. It is rare to find electrocatalysts for methanol oxidation in acidic media because its mechanism is not fully understood yet. In this research, HNO₃ exfoliated graphite powder and iron oxide composites have been synthesized by facile, single-step hydrothermal method. This procedure replaces the long and hazardous route of synthesizing graphene oxide. These composites not only provide large surface area for electrode reactions but also utilize catalytic and electrical capabilities of graphene and iron synergistically. Samples were characterized with FTIR, XRD, and SEM analyses while electrocatalytic efficiencies were studied with cyclic voltammetry and electrochemical impedance spectroscopy. Composites have shown remarkable efficiencies for oxidation of methanol in acidic media.

Graphical Abstract

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来源期刊

Electrocatalysis CHEMISTRY, PHYSICAL-ELECTROCHEMISTRY

CiteScore

4.80

自引率

6.50%

发文量

审稿时长

>12 weeks

期刊介绍： Electrocatalysis is cross-disciplinary in nature, and attracts the interest of chemists, physicists, biochemists, surface and materials scientists, and engineers. Electrocatalysis provides the unique international forum solely dedicated to the exchange of novel ideas in electrocatalysis for academic, government, and industrial researchers. Quick publication of new results, concepts, and inventions made involving Electrocatalysis stimulates scientific discoveries and breakthroughs, promotes the scientific and engineering concepts that are critical to the development of novel electrochemical technologies. Electrocatalysis publishes original submissions in the form of letters, research papers, review articles, book reviews, and educational papers. Letters are preliminary reports that communicate new and important findings. Regular research papers are complete reports of new results, and their analysis and discussion. Review articles critically and constructively examine development in areas of electrocatalysis that are of broad interest and importance. Educational papers discuss important concepts whose understanding is vital to advances in theoretical and experimental aspects of electrochemical reactions.