Sensing with Precision: The R2-Fluorescent Probe as a Smart Tool for Metal Ion Detection.

Abstract

We present the synthesis, characterisation, and application of a novel R2-based fluorescent probe for selective metal ion detection. Comprehensive studies using UV-Vis absorption and photoluminescence spectroscopy revealed strong binding with cobalt (Co²⁺) and aluminium (Al³⁺) ions, with a 2:1 binding stoichiometry (probe: metal) and with a detection limit as low as 5.5 × 10^-8 mol/L for aluminium and 3.2 × 10^-8 mol/L for cobalt, highlighting its remarkable sensitivity. With no interference from other metal ions, the probe showed outstanding stability and selectivity over a broad pH range. Analyses of actual water samples verified its usefulness in environmental monitoring. To further demonstrate the probe's potential in sophisticated sensing applications, it was also used to build a molecular logic gate. The experimental results were theoretically supported by Density Functional Theory (DFT) calculations, which also shed light on the binding mechanism. The R2 probe is emphasised in this work as a sensitive, specific, and adaptable instrument for environmental analysis and metal ion detection.