Polymerization-Induced Self-Assembly for the Synthesis of Polyisoprene-Polystyrene Block and Random Copolymers: Towards High Molecular Weight and Conversion

IF 4.3 3区 化学 Q2 POLYMER SCIENCE Macromolecular Rapid Communications Pub Date : 2025-02-06 DOI:10.1002/marc.202570009
Maryam Moradi, Prokopios Georgopanos
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Abstract

Back Cover: In article 2400727, Maryam Moradi and Prokopios Georgopanos present the synthesis of polyisoprene (PI) homopolymers, polyisoprene-polystyrene (PI-PS) block and random copolymers via RAFT-PISA polymerization in water. Using a poly(methacrylic acid) macroRAFT agent, PI and PI-PS copolymers with high monomer conversion are achieved. Thorough characterization indicated the successful synthesis, emphasizing PISA's scalability for producing tailored PI-PS copolymers with tailored-made molecular characteristics.

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聚合诱导自组装合成聚异戊二烯-聚苯乙烯嵌段和无规共聚物:迈向高分子量和转化
后盖:在2400727号文章中,Maryam Moradi和Prokopios Georgopanos介绍了在水中通过RAFT-PISA聚合合成聚异戊二烯(PI)均聚物、聚异戊二烯-聚苯乙烯(PI- ps)嵌段共聚物和无规共聚物。使用聚甲基丙烯酸(ma) macroRAFT剂,可获得PI和PI- ps共聚物,单体转化率高。全面的表征表明了成功的合成,强调了PISA在生产具有定制分子特征的定制PI-PS共聚物方面的可扩展性。
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来源期刊
Macromolecular Rapid Communications
Macromolecular Rapid Communications 工程技术-高分子科学
CiteScore
7.70
自引率
6.50%
发文量
477
审稿时长
1.4 months
期刊介绍: Macromolecular Rapid Communications publishes original research in polymer science, ranging from chemistry and physics of polymers to polymers in materials science and life sciences.
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